We report here the synthesis, electrochemical and photophysical properties of a series of novel exTTF-based organic dyes (3 and 7a,b) as well as their application in dye-sensitized solar cells (DSSCs). In the three designed dyes, the electron-donor exTTF group is connected to the rhodanine-3-acetic acid electron-acceptor unit through vinyl or vinyl-thiophene spacers. The electrochemical studies...

In this paper we designed and prepared three free-metal organic days Dye 1, Dye 2 and Dye 3 based on indoline with n-phenly substituents iminodibenzyl as the electron donor group. We used cyanoacrylic acid substituent as the electron acceptor anchoring group in organic dyes. The proposed dyes were prepared from iminodibenzyl as the starting material by standard reactions and characterized by di...

Advances in solar cell technology require designing of new organic dye sensitizers for dye-sensitized solar cells with high power conversion efficiency to circumvent the disadvantages of silicon-based solar cells. In silico studies including quantitative structureproperty relationship analysis combined with quantum chemical analysis were employed to understand the primary electron transfer mech...

Synthetic dyes comprise a large group of organic, organic salt and organometallic compounds which number in the thousands. Most individual dyes are assigned colour index (CI) numbers which helps to identify structure and properties as well as identity where a series of names have been used by the manufacturers for the same dye. Pigments are also listed and can be either organic or inorganic in ...

In the present study, comparison of  photocatalytic activity of nanostructures semiconductor zinc oxide (ZnO) was prepared using the different methods on the degradation of organic dye such as methylene blue that was investigated. Previous studies have proved that such semiconductors can degrade most kinds of persistent organic pollutants, such as detergents, dyes, pesticides and volatile organ...

In this study, Pt3Ni microspheres consisted of nanoparticles were synthesized without addition of surfactants via the solvothermal route. The obtained sample was characterized by X-ray diffraction (XRD), inductively coupled plasma-atomic emission spectrometer (ICP-AES), X-ray photoelectron spectroscopy (XPS), and field-emission scanning electron microscopy (FESEM). Furthermore, the catalytic pe...

Background: Organic dyes are used for a wide variety of purposes including their applications in textiles, foods, printing cosmetics and pharmaceuticals. Thus, these are industrially very important and their analysis is always required before putting to particular use. Methods: To develop the extremely efficient thin layer chromatographic system for the resolution of co-existing dyes, the silic...

In this study, four arylazobenzylidene dyes (a-d) were synthesized with excellent yields in two steps using Knoevenagel condensation and azo-coupling reactions. Absorption spectra of these dyes with different substituents were investigated in organic solvents as a function of solvent polarity. The spectral features of synthesized arylazobenzylidene dyes were described according to azo-hydrazone...

In this paper, we designed and synthesized free-metal dyes based on indoline. The proposed dyes were synthesized from phenothiazine as the starting material by standard reactions. The chemical structure of the synthesized dye was confirmed using FT-IR, 1HNMR and DSC techniques. Spectrophotometric measurements of the organic dyes in acetonitrile and on a TiO2 substrate ...

In the present study, comparison of  photocatalytic activity of nanostructures semiconductor zinc oxide (ZnO) was prepared using the different methods on the degradation of organic dye such as methylene blue that was investigated. Previous studies have proved that such semiconductors can degrade most kinds of persistent organic pollutants, such as detergents, dyes, pesticides and volatile organ...