A new dealkylation reaction between organophosphate esters and Salen aluminum bromide compounds has been used to prepare three new aluminum salen compounds salen((t)Bu)AlOP(O)Ph2 (1) (salen = N,N'-ethylenebis(3,5-di-tert-butylsalicylideneimine)), [(MeOH)Alsalen((t)Bu)[OMePO2(O)]Alsalen((t)Bu)[OMePO2(O)]Alsalen((t)Bu)]Br (2), and [salpen((t)Bu)AlO]2[(BuO)2PO]2 (3) (salpen = N,N'-propylenebis(3,5...

We synthesized Al-containing acidic and basic (alkaline) sodium aluminum phosphates (SALPs) which are FDAapproved leavening and emulsifying agents, respectively, and used them to determine the oral bioavailability of aluminum incorporated in selected foods. We selected applicable methods from published syntheses (patents) and scaled them down ( 3000and 850-fold) to prepare 300–400 mg of each SA...

Phosphorus (P) runoff from fields fertilized with swine (Sus scrofa domesticus) manure may contribute to eutrophication. The objective of this study was to evaluate the effect of aluminum sulfate (alum) and aluminum chloride applications to swine manure on P runoff from small plots cropped to tall fescue (Festuca arundinacea Shreb.). There were six treatments in this study: (i) unfertilized con...

This article describes investigations on the phase development (T ≤ 1500℃) of phosphate-bonded Al2O3-MgAl2O4 high-temperature ceramics by a combination solid-state MAS NMR and X-ray diffraction analyses. The ceramic body was bonded with inorganic hydrogen orthophosphates (Al, Mg, Ca, Zr) total binder content 3 wt.% P2O5. binding mechanisms these could be extensively deduced analyses development...

Sodium pyrophosphate (pyro-P, Na4P2O7), sodium tripolyphosphate (tripoly-P, Na5P3O10), and sodium hexametaphosphate (meta-P, (NaPO3)6) were selected as the model compounds of condensed phosphate to investigate the adsorption behavior of condensed phosphate on aluminum hydroxide. The adsorption was found to be endothermic and divisible into two stages: (1) fast adsorption within 1 h; and (2) slo...

backgrounds and aims: aluminum and in particular its compounds make up a large proportion of the pollutants coming from the aluminum foundry. in several studies conducted on the harmful effects of aluminum in recent decades, it has been identified as a neurotoxic metal. chronic occupational exposure through inhalation of dust is a common problem in aluminum foundries. investigation of the expos...

Fabrication and characterization of aluminum matrix composites containing different volume fractions of Ni3Al powder (5-40 Vol%) were investigated. Ni3Al powder was produced by mechanical alloying of elemental nickel and aluminum powder mixture. Al-Ni3Al composite parts were prepared using a powder metallurgy route involving two stages Al and Ni3Al powder mixtures were first compacted under 500...

Fabrication and characterization of aluminum matrix composites containing different volume fractions of Ni3Al powder (5-40 Vol%) were investigated. Ni3Al powder was produced by mechanical alloying of elemental nickel and aluminum powder mixture. Al-Ni3Al composite parts were prepared using a powder metallurgy route involving two stages Al and Ni3Al powder mixtures were first compacted under 500...