The replacement of plastic packaging by paperboard can significantly contribute to meeting sustainability goals in important application fields, such as food packaging. (water) barrier properties paperboard-based products need, however, be improved. Waterborne coatings offer an environmentally friendly possibility enhance these properties, which turn highly depend on the coating chemistry and f...

This study presents a new bionanocomposite coating on poly(ethylene terephthalate) (PET) made of pullulan and synthetic mica. Mica nanolayers have a very high aspect ratio (α), at levels much greater than that of conventional exfoliated clay layers (e.g., montmorillonite). A very small amount of mica (0.02 wt %, which is ϕ ≈ 0.00008) in pullulan coatings dramatically improved the oxygen barrier...

Abstract. We examine the sequence of local minimizers of the log-barrier function for a nonlinear program near a solution at which second-order sufficient conditions and the Mangasarian-Fromovitz constraint qualifications are satisfied, but the active constraint gradients are not necessarily linearly independent. When a strict complementarity condition is satisfied, we show uniqueness of the lo...

Superhydrophobic polymethylene (PM) films provide remarkable protection against the transport of aqueous redox probes as a result of entrapped air at the water/polymer interface. The wetting properties and the topography for a set of superhydrophobic (SH) and nonsuperhydrophobic (NSH) PM films were established to compare their interfacial behavior using electrochemical impedance spectroscopy (E...