Interactions of cationic tetrakis (N,N´,N´´,N´´´-tetramethyltetra-3,4-pyridinoporphyrazinatocobalt(II) (Co(tmtppa)) with synthetic polynucleotides, poly(A-T), poly(G-C) and calf thymus DNA have been characterized in 5 mM phosphate buffer, pH 7.2, by optical absorption and fluorescence spectroscopy. The appearance of hypochromicity effect and the red shift in UV-Vis spectrum of porphyrazine was ...

poly aromatic hydrocarbons are hydrophobic organic compound found as major contaminants in soil. soil biological activities are vital for the restoration of soil contaminated with hydrocarbons. successful application of bioremediation technology to contaminated soil requires knowledge of the characteristics of the site and the parameters that affect the microbial biodegradation of pollutants. t...

We have reported the use of carboxylate-alumoxanes as efficient nucleating agents for isotactic polypropylene (iPP) with a possible structural correlation to the nucleation efficiency. The unique, butterfly-like structure of carboxylate-alumoxanes correlates well with the nucleation characteristics of iPP and, for the first time, the impact of a thermally induced, crystalline transition of carb...

In the present work, large deformation rate-dependent constitutive behavior of isotactic polypropylene is studied via an experimentally validated macroscale model. To analyze nonlinear response material, mechanical tests are conducted at room temperature and a phenomenological model proposed to describe viscoplastic yielding damage semicrystalline polymer. The based on finite elastic-viscoplast...