A highly efficient Pd-catalyzed ortho-alkenylation is reported using a mono-phosphoric acid-directing group for the first time. This phosphoric acid-directing group is successfully utilized for the synthesis of various alkenylated products and offers a new approach to transition-metal-catalyzed C-H activation.

Nano silica-H2SO4 is an efficient and mild catalysis system for the regeneration of aldehyde from aldoximes. Ketoximes are converted to amides by Beckmann rearrangement in the presence of nano silica-H2SO4. The reactions are carried out in solvent-free conditions under microwave irradiation (600 W) within 50-120 sec in good yields.

an efficient green route for the preparation of naphthoxazinones, applying a three-component one-pot condensation reaction of 2-naphthol, aromatic aldehyde and urea in the presence of nano silica supported ferric chloride under solvent-free conditions has been developed. the present procedure offers several advantages such as short reaction time, simple workup, recovery and reusability of the c...

In this study, SBA-15-PAMAM mesoporous Nano-adsorbent was synthesized, characterized and applied for adsorption of Acid dyes (Acid Blue 62 (AB62) and Acid Red 266 (AR266)) from aqueous Medias. Adsorption of AB62 and AR266 on SBA-15 ordered mesoporous silica, polyamidoamine functionalized SBA-15(SBA-15-PAMAM), has been investigated. In order to assess the synthesized adsorbent constructional, FT...

In this research work, silica nano-porous thin films were deposited on glass substrates by layer by layer method. The thin films were calcinated at various calcination temperatures (200, 300, 400, and 500 °C). The morphology, surface characteristics, surface roughness and hydrophilic properties of the thin films were investigated by field emission scanning electron microscopy, attenuated total ...

Acid-based geopolymers are known for their high temperature resistance and good mechanical performances. Some compositions also exhibit water resistance, which make them suitable outdoor applications. This work aims to understand accurately the steps occurring during geopolymerization process focuses on type of networks forming at early stages reaction. The sample, prepared from metakaolin phos...

Nano silica-H2SO4 is an efficient and mild catalysis system for the regeneration of aldehyde from aldoximes. Ketoximes are converted to amides by Beckmann rearrangement in the presence of nano silica-H2SO4. The reactions are carried out in solvent-free conditions under microwave irradiation (600 W) within 50-120 sec in good yields.

As a raw material, phosphorus availability in agriculture has been critical concern terms of phosphate rock consumption related to price-dependent supply-demand chain. Novel approaches have proposed for alternative sources agricultural applications. Although nano-hydroxyapatite (nHA) is commonly used bioceramic its utilization as an fertilizer emerging field. Phosphogypsum (PG), by-product wet ...

Using template-containing silica microspheres as a precursor, novel ordered mesoporous silica nanoparticles with a narrow pore size distribution and high crystallinity have been synthesized by various hydrothermal merging processes. Several architectures like chains, dumbbells, triangles, squares and flowers have been discovered. The linking mechanisms of these interacting silica spheres leadin...

Cellulose is the most abundant biopolymer in nature and has a broad range of applications in the pharmaceutical, food and biomedical fields. This review article describes the functionalization conditions, crosslinking agents, reaction pathways and the resulting physicochemical and mechanical properties of functionalized cellulose derivatives. The discussion is focused on aqueous reactions and c...