Orange single crystals of new polymeric cobalt(II) complex {[Co(bipy)(H2O)4]2[Co(μ-mell)(H2O)2]·10H2O}n, 1, were synthesized by slow evaporation method at room temperature (bipy = 2,2′-bipyridine, mell hexaanion mellitic acid) and its crystal structure was determined single-crystal X-ray diffraction. The 1 characterized based on elemental analysis, FTIR spectroscopy thermal (TG/DTA) analysis fo...

we investigate the temperature-dependences of the Brillouin frequency shift in three different kind of single-mode fibers using a heterodyne method for sensing temperature. Positive dependences coefficients of 0.77, 0.56 and 1.45MHz/0C are demonstrated for 25 km long single-mode fiber, 10 km long non-zero dispersion shifted fiber and 100 m photonic crystal fiber, respectively. The results indic...

Photocatalysis has attracted significant attention as a potential issue for the degradation of toxic organic pollutants such as Congo Red. In this research spherical Pure ZnO nano particles and Ni-Co-ZnO nano composites (Zn0.95Ni0.04Co0.01O,  Zn0.95Ni0.025Co0.025O and  Zn0.95Ni0.01Co0.04O) have been synthesized by precipitation method. X- ray diffraction, Fourier transform Infra Red ,field emis...

The structure of the nonaaquayttrium (III) bromate, [Y(H2O)9](BrO3)3, at low temperature (100 K) has been studied by means of single-crystal X-ray diffraction. Crystallography shows a hexagonal unit cell, space group P63/mmc (No. 194) with Z = 2, a = b = 11.7104(11) Å, c = 6.6259(5) Å and V = 786.90(12) Å3 at 100 K. The hydra...

The heat of adsorption and sticking probability of CO on well-defined Pd nanoparticles were measured as a function of particle size using single crystal adsorption microcalorimetry. Pd particles of different average sizes ranging from 120 to 4900 atoms per particle (or from 1.8 to 8 nm) and Pd(111) were used that were supported on a model in situ grown Fe(3)O(4)/Pt(111) oxide film. To precisely...

The para-aminobiphenyl compound [(η(6)-C(6)H(5))(C(6)H(4)-4-NH(2))]Cr(CO)(3) (1) has an arene-phenyl dihedral angle of 38.01(6)°, as determined by single-crystal X-ray crystallography, and 34.7(11)°, as determined by DFT calculations. It undergoes haptotropic rearrangement at 140 °C in solution to form [(η(6)-C(6)H(4)-4-NH(2))(C(6)H(5))]Cr(CO)(3) (2), even though previous reports have suggested...

At room temperature, pure Co has a hexagonal close-packed (HCP) structure. When several percent of Fe is doped into crystal, it changes to the face-centered cubic (FCC) However, not clear why FCC structure in FexCo1−x system so stable even with small amounts concentration. Therefore, we carried out X-ray fluorescence holography (XFH) on Fe0.08Co0.92 single crystal visualize three-dimensional at...

130 years after Mond discovered the first homoleptic carbonyl complex Ni(CO)4, we report on a [Ni(CO)4].+ salt as synthesis of any nickel cation in condensed phase. It was prepared by oxidation metal with synergistic oxidant Ag[F{Al(ORF)3}2]/0.5 I2 (RF=C(CF3)3) CO atmosphere. This D2d-symmetric metalloradical represents last missing entry among structurally characterized cations Groups 6 to 11....