New relationships among the low-temperature alkali feldspars were deduced in part and implied in whole by recent crystal structure analyses of low and high albite and consideration of the electrostatic charge distributions in all the known alkali feldspar structures by Ferguson, Traill & Taylor. In general the most stable low-temperature forms are not those most highly ordered with respect to A...

This thesis deals with low symmetry effects in the crystal (ligand) field theory and related spectroscopic studies. Firstly, the background theory underlying the low symmetry effects in crystal field theory and spectroscopic studies is reviewed. This includes crystal field Hamiltonian, spin Hamiltonian, zero-field splitting Hamiltonian, various operator and parameter notations, the experimental...

Nematic phase transitions in high-temperature superconductors have a strong impact on the electronic properties of these systems. BaFe$_2$As$_2$,\@ with an established nematic transition around 137 K induced by magnetic fluctuations, and BaNi$_2$As$_2$,\@ non-magnetic analog BaFe$_2$As$_2$ structural same temperature range,\@ share common tetragonal aristotype crystal structure space-group type...

Acluster[ pt (Reo )(?-dppm) ][Reo ],2 [dppm=ph Pch ] with oxidaton of [pt Re(CO) ](?-dppm) ][PF ] is prepred . Crystals are triclinic,pl; a= 14.154(4)?, b=14.213(3) ?,c = 20.522(4) ? , a = 78.938(14)?, ?= 75.812(19) ? , ?= 74,957(22) ? ;v = 3828.9(1 5) ? ,z =2 ; Eraf-Noniu CAD4 difhctorneter with Mo- K radiation, ? = 0.71073 ? ; R = 0.069, R = 0.077 for 284 parameters and 5414 reflect...

The centrosymmetric title compound, C(18)H(28)I(2)O(2), crystallized in the monoclinic space group P2(1)/c with the alkyl chains having extended all-trans conformations, similar to those in the centrosymmetric bromo analogue [Li et al. (2008 ▶). Acta Cryst. E64, o1930] that crystallized in the triclinic space group P. The difference between the two structures lies in the orientation of the two ...

The title compound, [CoFe(C5H5)(C16H14N2O2)(C11H9N2O)], was prepared as an air-stable red-brown solid by mixing equimolar amounts of {2,2'-[ethane-1,2-diylbis(nitrilo-methanylyl-idene)]diphenolato}cobalt(II) and N-ferrocenylisonicotinamide in dry di-chloro-methane under nitro-gen and was characterized by ESI-MS, IR, and single-crystal X-ray diffraction. The structure at 100 K has triclinic (P-1...

We analyze the stability of laminated microstructure for martensitic crystals that undergo cubic to trigonal, orthorhombic to triclinic, and trigonal to monoclinic transformations. We show that the microstructure is unique and stable for all laminates except when the lattice parameters satisfy certain identities.

Tetracarbonyl(2,2'-dipyridylamine)tungsten was prepared from W(CO)6 and 2,2'-dipyridylamine in toluene. The structure was determined by an X-ray diffraction analysis. Crystal data: triclinic; space group, P-1 (No.2); a = 8.454(1)A, b = 13.369(2)A, c = 6.9452(9) A, a= 85.88(1) degrees, beta = 68.28(1) degrees, gamma = 80.93(1) degrees, V= 720.0(1)AI; Z = 2.