نتایج جستجو برای: variable temperature kinetic
تعداد نتایج: 774975 فیلتر نتایج به سال:
The concept of temperature is one of the key ideas in describing the thermodynamical properties of a physical system. In classical statistical mechanics of ideal gases, the notion of temperature can be described in two different ways, the kinetic temperature and the thermodynamic temperature. For the Boltzmann distribution, the two notions lead to the same result. However, for a general probabi...
The uncertainties inherent to experimental differential scanning calorimetric data are evaluated. A new procedure is developed to perform the kinetic analysis of continuous heating calorimetric data when the heat capacity of the sample changes during the crystallization. The accuracy of isothermal calorimetric data is analyzed in terms of the peak-to-peak noise of the calorimetric signal and ba...
for fighting with blights and studying on effect of thickness, two experiments were done. the first series were included independent variable ages of blight in four levels (age1,age2,age3 and age4) and the thermal care temperature in four levels(10,15,20 and 30 seconds) and the dependent variable is death rate . the second series were included independent variables thermal care temperature in t...
in the present study, mixed convection laminar flow around an adiabatic body in a lid-driven enclosure filled with nanofluid using variable thermal conductivity and variable viscosity is numerically investigated. the fluid around the body in the enclosure is a water-based nanofluid containing al2o3 nanoparticles. the vertical enclosure’s walls are maintained at constant cold temperature and the...
The time history of the local ion kinetic energy in a stagnating plasma was determined from Doppler-dominated line shapes. Using independent determination of the plasma properties for the same plasma region, the data allowed for inferring the time-dependent ion temperature, and for discriminating the temperature from the total ion kinetic energy. It is found that throughout most of the stagnati...
In this study, an in-house multi-dimensional code has been developed which simulates the combustion of n-heptane in a Homogeneous Charge Compression Ignition (HCCI) engine. It couples the flow field computations with detailed chemical kinetic scheme which involves the multi-reactions equations. A chemical kinetic scheme solver has been developed and coupled for solving the chemical reactions an...
The reaction of CH3O2 radicals with acetaldehyde on the solid surface of NH4NO3 has been studied in a flow capillary reactor at low pressure and room temperature. The experiments were performed using EPR spectrometer combined with the kinetic method of radicals freezing. Peroxy radicals revealed an oscillation complex behavior during the process regarding to the phenomenon of radicals multiplic...
Reaction behaviors and kinetics of catalytic oxidation of toluene with different feed flows over Pt/Zr(x)-HMS catalysts with Si/Zr ratio equal to 5, 10, 20 and 35 were investigated over a wide temperature range (200 – 500 oC). Results show that Pt/Zr(x)-HMS performs more easily toluene oxidation. The kinetic data were fitted by the Power-law and Mars–van Krevelen kinetic models. The fitting res...
The effect of temperature and calcium ions on the denaturation of a recombinant alpha-amylase from Bacillus halmapalus alpha-amylase (BHA) has been studied using calorimetry. It was found that thermal inactivation of BHA is irreversible and that calcium ions have a significant effect on stability. Thus an apparent denaturation temperature ( T (d)) of 83 degrees C in the presence of excess calci...
A theoretical framework for prediction of the dynamic evolution of chemical species in DNA amplification reactions, for any specified sequence and operating conditions, is reported. Using the polymerase chain reaction (PCR) as an example, we developed a sequence- and temperature-dependent kinetic model for DNA amplification using first-principles biophysical modeling of DNA hybridization and po...
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