The effect of the ionic strength on adsorption of Cu on calcium montmorillonite was studied at concentrations ranging from 31 to 516 microM. An adsorption model was employed in the analysis of the data. When the background electrolyte was NaClO4, the ionic exchange was suppressed at 0.5 M concentration, and Cu adsorption took place on edge sites, reaching a plateau at about 24 mmol/kg. A furthe...

OBJECTIVES In this study, we investigated the influence of ionic strength and natural organic matter (NOM) on aggregation and soil adsorption of citrate-coated silver nanoparticles (AgNPs). METHODS Time-resolved dynamic light scattering measurements and batch adsorption experiments were used to study their aggregation and soil adsorption behaviors, respectively. RESULTS The aggregation rate...

Phospholipase B (lysolecithin acyl-hydrolase, EC 3.1.1.5) from the mycelia of Penicillium notatum (Institute for Fermentation, Osaka, Japan; No.4640) was adsorbed from a crude solution to palmitoyl cellulose. Adsorption was efficient at pH 4 at low ionic strength (10 mM buffer), and at pH 4-9 at higher ionic strength (1-2M NaCl in 10 mM buffer). The adsorbed enzyme was eluted from the cellulose...

As(V) adsorption onto a commercially available TiO2 (Degussa P25) in NaCl or NaClO4 at various concentrations (0.001-0.1 M) was investigated. The effect of natural organic matter (NOM) on As(V) removal through the adsorption by TiO2 was also examined. In either electrolyte, As(V) adsorption onto TiO2 increased with the increase of ionic strength under alkaline conditions (pH 7.0-11.0). Under ac...

We review recent experiments on the interaction of proteins with anionic polyelectrolytes in aqueous solution. Data from the literature demonstrate that proteins can form soluble complexes with linear polyelectrolytes even on the "wrong side" of the isoelectric point, that is, for pH values above the isoelectric point of the proteins under which the polyelectrolytes and the proteins are like-ch...

introduction: boron is one of the eight essential micronutrients required for plant growth and development. the optimal concentration range (between deficiency and phytotoxicity) for boron is narrower than for other plant essential nutrients. generally, irrigating water containing concentrations of b greater than 1 mg l-1 would be detrimental for most plants. although, there are a large number ...

We contrast the adsorption, over a wide range of pH and ionic strength, of polyelectrolyte chains with different fractions of charged segments but similar degree of polymerization. The system was a cationic polymer, poly~1,4 vinyl!pyridine ~PVP!, with 14%, 48%, and 98% quaternized repeat units, adsorbed from aqueous solution ~D2O or H2O! onto a single silicon oxide substrate at 25 °C. Measureme...