The transition from invertebrate calcium carbonate-based calcite and aragonite exo- and endoskeletons to the calcium phosphate-based vertebrate backbones and jaws composed of microscopic hydroxyapatite crystals is one of the great revolutions in the evolution of terrestrial organisms. To identify potential factors that might have played a role in such a transition, three key domains of the vert...

Methoxy poly(ethylene glycol) (mPEG) with molecular mass of 5 kDa activated with succinimidyl carbonate and cyanuric chloride, separately was covalently attached to human red blood cells (RBCs). Inhibition of agglutination by blood-type specific antisera (anti-D) was employed to evaluate the effect of the polymer coating. The remaining single cells after incubation with anti-D sera were cou...

Lithium-ion battery performance is strongly influenced by the ionic conductivity of the electrolyte, which depends on the speed at which Li ions migrate across the cell and relates to their solvation structure. The choice of solvent can greatly impact both the solvation and diffusivity of Li ions. In this work, we used first-principles molecular dynamics to examine the solvation and diffusion o...

This work investigates the influence of soil type on electrodialytic remediation (EDR) of lead (Pb). In electrokinetic soil remediation, it is well known that pH is a key factor and that carbonate influences remediation efficiency negatively. This work provides results from laboratory-scale EDR experiments with ten representative industrially Pb-contaminated surface soils. Results indicate that...

Hussainsagar lake in the heart of Hyderabad city receives domestic sewage and industrial effluents through five streams draining the catchment area of 245 sq. km around the lake. Lake used to receive untreated industrial effluents through streams during 1970 -1990. Over the years, sediments in the lake have adsorbed the heavy metals and have reported elevated concentrations. Metal speciation of...

The titaniumoxoanion complex [(Et2O)2Li][OTi(N[ tBu]3,5-Me2C6H3)3] ([(Et2O)2Li][1]) reactswithCO2 indiethyl ether to form the carbonate complex ([Li][O2COTi(N[ tBu]3,5-Me2C6H3)3])6 ([Li][2]). The solidstate structure of complex [Li][2] is a hexamer with a hexagonal prismatic core comprised of six lithium cations bridgedby the carbonate functionality. In themonomeric subunits of [Li][2], the car...

Serum transferrin is a key player in iron homeostasis, and its ability to deliver iron to cells via the endosomal pathway critically depends on the presence of carbonate that binds this protein synergistically with ferric ion. Oxalate is another ubiquitous anionic species that can act as a synergistic anion, and in fact its interaction with transferrin is notably stronger compared to carbonate,...

Uranium is a chemically toxic and radioactive heavy metal. Depleted uranium (DU) the byproduct of enrichment process, with majority U as uranium-238, lower content fissile isotope uranium-235 than natural uranium. Uranium-235 mainly used in nuclear reactors manufacture weapons. Exposure likely to have an impact on humans or ecosystem where military operations DU. Yuma Proving Ground Arizona, US...