abstract a study was conducted to evaluate the effect of incubation time, sewage sludge and clay content on the distribution of nickel and cadmium in different fractions of selected calcareous soils. to meet this purpose, an experiment with two different soils (4 and 30 percent caco3), two different textures (8 and 40 percent clay), two levels of nickel (0 and 100 mg.kg-1), two levels of cadmiu...

Measurements of electrochemical (EC) arsenite oxidation demonstrated thatthe arsenite oxidation current increased in the presence of carbonate while the potential of the onset of EC arsenite oxidation exhibited a strong shift toward less positive values. Examination of pH and total carbonate concentration effects on the EC arsenite oxidation parameters showed that they were affected solely by t...

abstract zinc (zn) is an essential plant nutrient. knowledge about distribution of zn between its different chemical forms is useful in understanding the chemistry of this element in soil and also in development of soil testing procedures. the present study was conducted to obtain such information about distribution of zinc forms in 20 soil samples of lorestan province by the use of a sequentia...

Copper-zinc superoxide dismutase (SOD) is of fundamental importance to our understanding of oxidative damage. Its primary function is catalysing the dismutation of superoxide to O(2) and H(2)O(2). SOD also reacts with H(2)O(2), leading to the formation of a strong copper-bound oxidant species that can either inactivate the enzyme or oxidise other substrates. In the presence of bicarbonate (or C...

An azacryptand has been solubilised in aqueous media containing 50% (v/v) dimethyl sulphoxide. (13)C-NMR has been used to determine how the azacryptand is affected by zinc binding at pH 10. Using (13)C-NMR and (13)C-enriched bicarbonate we have been able to observe the formation of 4 different carbamate derivatives of the azacryptand at pH 10. The azacryptand was shown to solubilise zinc or cad...

Currently, few studies have investigated sediment phosphorus (P) pools or identified the chemical processes important in the P cycle of fine-grained carbonate sediments, particularly in coastal estuaries with high organic matter. To determine the role of fine-grain calcium carbonate and high organic matter on sedimentary P, we investigated the solid-phase P pools in seagrass sediments of north-...

The complexation of Cm(III) with transferrin is investigated in the pH range from 3.5 to 11.0 in the absence of carbonate and at c(carbonate)tot = 25 mM. In the absence of carbonate two Cm(III) transferrin species I and II are formed depending on pH. An increase of the total carbonate concentration favors the formation of the Cm(III) transferrin species II with Cm(III) bound at the Fe(III) bind...