The self-discharge of hybrid electrochemical capacitors based on the redox activity of electrolyte additives or grafted species to the electrode material is investigated simultaneously for the cell and each individual electrode. Electrochemical capacitors using a redox-active electrolyte consisting in hydroquinone added to the electrolyte solution and a redox-active electrode based on anthraqui...

the electrochemistry of banana tissues on a carbon paste electrode modified with multi-walled carbon nanotubes (mwcnts) is presented. cyclic voltammetry is applied to investigate the direct electrochemistry of banana tissues i.e. a source of polyphenol oxidase (ppo). a redox couple with an anodic and counterpart cathodic peak is obtained. the influence of various parameters such as ph, scan rat...

abstract background: heavy metals in industrial wastewater especially chromium (vi) are considered as the main environmental pollutants. methods: electrochemical cell made of plexiglass with a volume of 1.95 lit was used. iron and graphite electrodes, electricity conductor, each with dimensions of 0.1×3×10 cm (width×length×height) were designed and built. tests were carried out in various condi...

a novel chemically modified electrode containing prussian blue complex was achieved on the surface of glass carbon electrode by sol-gel technique. the electrochemical behavior of modified electrode was characterized by cyclic voltammetry in detail. the film electrode obtained was very stable and exhibited electrocatalytic response for oxidation of nitrite. results showed at bare gc electrode, a...

A novel electrochemical sensor was proposed for the determination of amitriptyline based on the copper oxide (CuO) nanoparticles modified graphite screen-printed electrode. CuO nanoparticles were used to enhance the surface area of the electrode and then improve the sensitivity of the electrochemical sensor. Amitriptyline electrochemical response characteristics of the modified electrode in a p...

In this study, pencil graphite electrode was modified using conductive polypyrrole (Ppy) and grapheme (GF) nanocomposite for electrochemical determination of insulin. Electrochemical behavior of insulin on PGE was investigated using cyclic voltammetric (CV) and differential pulse voltammetric (DPV) and chronoaprometry (CA) methods. Several effective parameters including pH, concentration, and s...

A novel electrochemical sensor was proposed for the determination of amitriptyline based on the copper oxide (CuO) nanoparticles modified graphite screen-printed electrode. CuO nanoparticles were used to enhance the surface area of the electrode and then improve the sensitivity of the electrochemical sensor. Amitriptyline electrochemical response characteristics of the modified electrode in a p...

The interaction of DNA with quercetin was studied using scanning electrochemical microscopy and electrochemical impedance spectroscopy at glass carbon electrode. Information such as the surface coverage of the film and apparent rate constant of the redox active probe in solution was obtained. It is deduced that quercetin interacting with DNA forms a kind of electrochemical inactive supramolecul...

Fabrication and electrochemical characterization of disposable working electrodes/transducers of electrochemical sensors is described in this work. The aim was to find the best electrochemical properties of screen-printed electrode substrates modified with multiwalled carbon nanotubes (MWCNTs) based active layers. Two types of platinum electrode contacts were investigated and the suitable thick...