The surface of mercapto-functionalized mesoporous silica having a highly ordered open pore network was modified into a super-hydrophilic surface through a stepwise sulfonation process involving oxidation and ionization reactions. The initial mesoporous silica was prepared using an acid-catalyzed sol-gel reaction between tetraethoxysilane (TEOS) and 3-mercaptopropyltrimethoxysilane (MPTMS) in th...

Mesopore walls of hierarchically meso-/microporous zeolites (MFI, BEA and LTA) are covered with silanol groups, so that the zeolites can be functionalized with various organic groups via silylation; the organic-functionalized hierarchical zeolites exhibit hydrothermal stability and reusability in catalytic applications, as compared with organic-functionalized mesoporous silica.

Hexagonal mesoporous silica (SBA-15) was prepared and then functionalized by(3-mercaptopropyl)trimethoxysilane. The obtained 3-mercaptopropyl functionalized SBA-15 (SBA-Pr-SH) was then oxidized using H2O2 in methanol under an acidic condition to give sulfonic acid functionalized mesoporous silica (SBA-Pr-SO3H). Th...

In this study, Santa Barbara Amorphous (SBA-15) mesoporous silica has been functionalized with aminopropyl groups that were converted to propargyl-bearing moieties through the reaction with propargyl bromide. The material then underwent an efficient Cu(I)-catalyzed azide alkyne click reaction with sodium azide in order to obtain the corresponding triazole products. The covalent modification of ...

In this study the effect of surface modification of mesoporous silica nanoparticles (MSNs) on its adsorption capacities and protein stability after immobilization of beta-lactoglobulin B (BLG-B) was investigated. For this purpose, non-functionalized (KIT-6) and aminopropyl-functionalized cubic Ia3d mesoporous silica ([n-PrNH2-KIT-6]) nanoparticles were used as nanoporous supports. Aminopropyl-f...

un Qian rash Gharibi ailing He hejiang University oint Research Center of Photonics of the Royal Institute of Technology Sweden and hejiang University entre for Optical and Electromagnetic Research ijingang Campus, Hangzhou 310058 hina Abstract. Protoporphyrin IX PpIX -encapsulated mesoporous silica nanoparticles were synthesized, characterized, and utilized for photodynamic therapy PDT of canc...

Large-pore mesoporous silica microspheres with tailored pore sizes were prepared via a two-step synthesis process by using a triblock copolymer EO20PO70EO20 as template in combination with a cosurfactant cetyltrimethylammonium bromide (CTAB) and a cosolvent ethanol. The obtained mesoporous silica spheres were characterized by scanning electron microscopy (SEM), transmission electron microscopy ...

A new method for the preparation of well-defined functionalized mesoporous SBA-15 has been developed by a one-step co-condensation method using trimethallylsilanes as organosilane sources. This new method enables the incorporation of various bulky organic functional groups with long alkyl chain tethers into the mesoporous silica network.

Distributed sensing of gas-phase chemicals is a promising application for mesoporous materials when combined with highly sensitive miniaturized gas sensors. We present a direct application of a mesoporous silica thin film on a highly sensitive miniaturized resonant chemical sensor with a mass sensitivity at the zeptogram scale for relative humidity and CO(2) detection. Using mesoporous silica t...

We report on a chemical-sensing method based on the silica-micelle mesophase wherein both a fluoroionophore and a masking agent are embedded. Using this method, a highly selective detection of metal ions in an aqueous solution has been successfully demonstrated. Furthermore, simultaneous analyses of multisamples using a sensor array composed of functionalized mesoporous thin films were demonstr...