the concept of resonance assisted hydrogen bond (rahb), which usually occurs in b diketons, has a remarkable role in chemistry. these molecules, which contain heteroatom particularly o and n, are species with biological interest in protein folding and dna pairing. therefore, the amplification of hydrogen bonds strength by substituents may be important in life sciences. in the current research, ...

hydrogen is seen as one of the important energy carriers of the future with potential to reduce local as well as global warming. the main by-product of the combustion of hydrogen in air is water vapor and trace quantities of oxides of nitrogen. an experiment was conducted to study the impact of hydrogen/natural gas blends on performance, thermodynamic efficiency and exhaust gas emissions in a r...

the one-dimensional model of lippincott and schroeder for hydrogen bond has been re-examined and it has been shown that o-h bond distance depends on repulsive van der waals and attractive electrostatic potentials.it has been shown that constant b in the van der waals repulsion potential is not transferable to all hydrogen bonds. the possibility of obtaining the semi-empircal parameters in the l...

microbial electrolysis cell (mec) is one of the promising and cutting-edge technologies for generating hydrogen from wastewater through biodegradation of organic waste by exoelectrogenic microbes. in the mecs, the operational parameters, such as applied voltage (eap), anode surface area, anode-cathode distance, and n2/co2 volume ratio have a significant impact on the hydrogen yield and producti...

in this paper, the electrochemical hydrogen storage in nanocomposite materials was studied. multi-walled carbon nanotubes (mwcnts) electrode was prepared by mixing with special composite. the optimum ratio of mwcnts was estimated 30-70% (w/w) in the composite material. mwcnts were synthesized by chemical vapor deposition (cvd). the nanocomposite was homogenized by microwave. cyclic voltammetry ...

hydrogen peroxide, an oxidizing agent used in surgery for its antiseptic properties, has been associated with life-threatening complications. we report a case of suspected gas embolism following irrigation of a tibial bone cyst with hydrogen peroxide in a five year-old boy under general anesthesia, who died despite resuscitative measures and a long stay in the intensive care unit.

a palladium composite membrane was prepared by electroless plating on oxidized porous stainless steel support (ox-pss). hydrogen permeation flux through this composite membrane was measured in the temperature range of 574-674k and the pressure difference of two sides of membrane up to 90kpa. a simplified resistance model was employed to analyze the permeation behavior of hydrogen through pd/ox-...