Abstract: Reduction of the Titanium dioxide, TiO2, by methane was investigated in this work. The thermodynamic of reaction was examined and found favorable. The reaction of titanium dioxide with methane was carried out in the temperature range 1150°C to 1450°C at atmospheric pressure with industrial high porosity pellets prepared from titanium dioxide powder. The evolved gas analyzing method wa...

-The present work is focused on the heterogeneous photocatalytic degradation of Amaranth dye over immobilized nano-crystals of TiO2. Immobilization has been an acceptable approach to overcome the drawbacks encountered with powder suspensions. Immobilization is performed using polyvinyl alcohol-formaldehyde binder. This method of immobilization does not require thermal heating at high temperatur...

This work describes the photocatalytic removal of methylene blue from aqueous solution by titanium dioxide nanoparticles under ultraviolet irradiation in a batch system. The effect of operational parameters such as irradiation time, nano titanium dioxide dosage, pH and initial methylene blue concentration were analyzed and optimized by response surface methodology in the nano titanium dioxide/u...

Titanium dioxide was applied as an immobilized photocatalyst in a microstructured falling film reactor for the continuous-flow C–H arylation of heteroarenes with aryldiazonium salts as the starting material. Detailed investigations of the catalyst and a successful long-term run proved its excellent usability for this process. Very good yields up to 99% were achieved with broad substrate scope a...

Titanium is a successful biomaterial that possesses good biocompatibility. It is covered by a surface layer of titanium dioxide, and this oxide may play a critical role in inhibiting reactive oxygen species, such as peroxynitrite, produced during the inflammatory response. In the present study, titanium dioxide was coated onto silicone substrates by radio-frequency sputtering. Silicone coating ...

Phospho-proteomics relies on methods for efficient purification and sequencing of phosphopeptides from highly complex biological systems using low amounts of starting material. Current methods for phosphopeptide enrichment, e.g., immobilized metal affinity chromatography and titanium dioxide chromatography, provide varying degrees of selectivity and specificity for phosphopeptide enrichment. Fu...

The photocatalytic degradation of a macrolide (tylosin) has been studied using immobilized titanium dioxide as photocatalyst in a laboratory reactor under UV illumination (365 nm). The degradation of the antibiotic and of the reaction intermediary product was monitored by UV spectrophotometry and HPLC. Three photocatalysts (P25 from Degussa and PC105 and PC500 from Millennium) immobilized on gl...

Strong adsorption of pollutants on activated carbon may inhibit their diffusion to the catalyst on the surface of the adsorbent and hence reduce he whole photocatalytic process. Oxidation of the carbon surface will change the adsorption properties of the carbon; and increase the capability of arbon surface to carry more titanium dioxide. In this work, activated carbon was oxidized with differen...

Pigment grade titanium dioxide is composed of sub-micron sized particles, including a nanofraction, and is widely utilized in food, cosmetic, pharmaceutical, and biomedical industries. Oral exposure to pigment grade titanium dioxide results in at least some material entering the circulation in humans, although subsequent interactions with blood immune cells are unknown. Pigment grade titanium d...