simple, low temperature and environmentally benign green route is proposed for preparation of nanocrystalline zno in presence of a low-cost and halide-free room-temperature ionic liquid (rtil) by refluxing at 95 °c for 60 minutes. the x-ray diffraction (xrd) studies display that the products are well-crystallized in the form of wurtzite hexagonal. morphology of the as-prepared zno was character...

A canonical ensemble model is used to describe a caloric curve of nuclear liquid-gas phase transition. Allowing a discontinuity in the freeze out density from one spinodal density to another for a given initial temperature, the nuclear liquid-gas phase transition can be described as first order. Averaging over various freeze out densities of all the possible initial temperatures for a given tot...

in this research, we have developed cheap recyclable and task-specific acidic ionic liquids (ails) 1-hydrogen-3-methylimidazolium hydrogen sulfate [hmim]hso4, 1-hydrogen-3-methylimidazolium chloride [hmim]cl, 2-pyrrolidonium hydrogensulfate [hnhp]hso4 and applied them in acid catalyzed synthesis of quinoxaline derivatives from 1,2-phenylendiamines and 1,2-dicarbonyl compounds. the products coul...

We combine density-functional theory with the string method to calculate the minimum free energy path of bubble nucleation in two polymer–CO2 mixture systems, poly(methyl methacrylate) (PMMA)–CO2 and polystyrene (PS)–CO2. Nucleation is initiated by saturating the polymer liquid with high pressure CO2 and subsequently reducing the pressure to ambient condition. Below a critical temperature (Tc),...

the three-phase-lag model and green–naghdi theory without energy dissipation are employed to study the deformation of a two-temperature fiber-reinforced medium with an internal heat source that is moving with a constant speed under a hydrostatic initial stress and the gravity field.  the modulus of the elasticity is given as a linear function of the reference temperature. the exact expressions ...

The influence of the initial fuel temperature on the burning behavior of n-heptane pool fire was experimentally studied at the State Key Laboratory of Fire Science (SKLFS) large test hall. Circular pool fires with diameters of 100mm, 141 mm, and 200 mm were considered with initial fuel temperatures ranging from 290 K to 363 K. Burning rate and temperature distributions in fuel and vessel wall w...

The optical switching times of liquid-crystal cells using 5CB, 5OCB and PCH5 liquid crystal materials have been characterized as a function of applied voltage, V, and temperature, T. The transition time from 90 to 10 % transmission scales as V and is limited to 50 to 30 ns by the breakdown electric field, ~ 10 V cm of the liquid crystal. The time from the initial voltage step to 90 % transmissi...

A one-dimensional model has been developed to investigate the thermal decomposition of rocket grade hydrogen peroxide (HP) in a stream of previously decomposed HP products. The model developed assumes steady, one-dimensional adiabatic flow and includes basic mass balances, droplet evaporation, gasphase decomposition kinetics, droplet dynamics, and control volume conservation laws. The code is a...