This paper describes a detailed study on the complexation of pyridinium derivatives with calixarenes bound to gold nanoparticles (AuNPs). The studied calixarene derivatives are mixed with alkanethiols to formmixed monolayers on AuNP surfaces. The key findings are: (i) even a small amount (less than 11 mol%) of calixarenes can retain their complexation abilities among a majority of alkanethiols ...

This study examines the adsorption isotherms, kinetics and mechanisms of Pb²(+) sorption onto waste cow bone powder (WCBP) surfaces. The concentrations of Pb²(+) in the study range from 10 to 90 mg/L. Although the sorption data follow the Langmuir and Freundlich isotherm, a detailed examination reveals that surface sorption or complexation and co-precipitation are the most important mechanisms,...

The observed variability of fluid chemistry at the Äspö Hard Rock Laboratory is not fully described by conservative fluid mixing models. Ion exchange may account for some of the observed discrepancies. It is also possible that variably charged solids such as oxyhydroxides of Fe can serve as sources and sinks of anions and cations through surface complexation. Surface complexation reactions on h...

The aqueous solubility of oxyanion (e.g. phosphates and arsenates), and thereby their mobility, bioavailability (phosphates) and toxicity (arsenates), in soils and sediments is dependent upon their chemical speciation. In complex, multicomponent systems, equilibrium modelling can be a useful tool to predict chemical speciation. When establishing a model, it is essential to understand the intera...

covalent grafting of mcm-41 with 3-chloropropyl trimethoxysilane and subsequent reaction respectively with acacdien and complexation with moo2(acac)2 afforded moo2acacdien@mcm-41. x-ray diffraction and nitrogen sorption analyses revealed the preservation of the textural properties of the support as well as accessibility of the channel system despite sequential reduction in surface area, pore vo...

Simulation of chemical element adsorption, release, and transport is possible without the need to perform time consuming, detailed adsorption studies on multiple samples by incorporating prediction equations into chemical speciation–transport models before simulating. Adsorption models also assume that the chemical species in a mixture is at chemical equilibrium which is the state in which the ...

Surface complexation models (SCMs) have been successfully used to describe metal ion adsorption on pure mineral materials. However, such models have rarely been applied to model adsorption on natural materials. In this study, the surface complexation model approach was used to describe the surface properties and adsorption behavior of natural aquatic sediment. Three typical versions of the surf...

Simulating adsorption of U(VI) under transient groundwater flow and hydrochemistry: Physical versus chemical nonequilibrium model" (2011). [1] Coupled intragrain diffusional mass transfer and nonlinear surface complexation processes play an important role in the transport behavior of U(VI) in contaminated aquifers. Two alternative model approaches for simulating these coupled processes were ana...

In this study, the adsorptive characteristics of biochar generated from anaerobically digested garden wastes (AD-char) were investigated. Metal adsorption onto AD-chars reached equilibrium in 48 h; the adsorption capacity of Cu by AD-char was 182 μmol g, which was higher than that of Zn (35.3 μmol g) and Mn (60.7 μmol g). The metal adsorption was well described by the pseudo second-order kineti...