vanadium supported on highly ordered nanoporous silica (vox-lus-1) was synthesized and characterized by xrd, nitrogen adsorption‑desorption isotherms and uv-visible spectrophotometer. direct oxidation of benzene to phenol in liquid phase by h2o2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). the maximum yield (25%) and selectivity (73%) of the ph...

Capture and recovery of hazardous air pollutants (HAPs) and volatile organic compounds (VOCs) from gas streams using physical adsorption onto activated carbon fiber cloth (ACFC) is demonstrated on the bench-scale. This system is regenerated electrothermally, by passing an electric current directly through the ACFC. The adsorbate desorbs from the ACFC, rapidly condenses on the inside walls of th...

Monosulfuron-ester is a new, low rate, sulfonylurea herbicide that is being promoted for annual broadleaf and gramineal weed control; however, there is a lack of published information on its behavior in soils. The adsorption and desorption of monosulfuron-ester by seven type soils were measured using a batch equilibrium technique. The results showed that the Freundlich equation fitted its adsor...

In this work we have analyzed the adsorption-desorption kinetics in the framework of the lattice gas model. We have shown that the coefficients representing the transition probabilities must be carefully chosen even when they fulfill the principle of detailed balance, otherwise the observables arising from the kinetics present anomalous behavior. We have demonstrated that when the adsorption Ai...

By using cyclodextrin (α-CD) self-assembly into a hydrogel with the triblock copolymer Pluronic F127, nanomicrocrystalline cellulose was introduced into a gel system to form a composite CNC-β-CD/α-CD/Pluronic F127 hydrogel (CCH). CCH was modified further by grafting acrylic acid to form a novel acrylated composite hydrogel (ACH). The swelling degree of ACH was 156 g/g. Adsorption isotherms show...

Madrid, L. and De Arambarri, P., 1978. Adsorption isotherms and hysteresis of proton adsorption by goethite. Geoderma, 21: 199-208. The adsorption of H+ions by goethite is only partially reversible and the adsorption process is faster than desorption. The adsorptian isotherm shows two inflexion points at pH y,alues 7.5 and 9.5, which can be attributed to the existence of two ar more types of OH...

Water vapor adsorption on activated carbon cloth (ACCBO) which has been oxidized to a level of 32% oxygen exhibits a unique isotherm with uniform hysteresis of small magnitude upon desorption. In contrast the adsorption on untreated ACCBO and chemically modified ACCBO (7.8% Cl), ACCBO (16% Cl), and ACCBO (4% N), exhibits sigmoidal isotherms with hysteresis loops of varying magnitudes. The latte...

Syringopicroside is the major constituent in Folium syringae leaves with known pharmacological activities. In this study, a simple method for preparative separation of syringopicroside from F. syringae leaves with macroporous resins was developed. Adsorption characteristics of syringopicroside on six types of macroporous resins, including ADS-8, ADS-17, D141, NKA-9, HPD450, and HPD600, have bee...

The adsorption of CO on polycrystalline TiO2 was investigated by static adsorption microcalorimetry. The initial differential heat of adsorption (qdiff,0) of CO on polycrystalline titania is 40 kJ/mol, and the standard adsorption entropy (Deltas0) is -104 J mol(-1) K(-1). These results are consistent with those derived from temperature-programmed desorption and FTIR results in the literature. T...

This paper presents a systematic study of the surface chemistry, porous texture and adsorptive characteristics of prepared new activated carbon using Persian mesquite grain. Several techniques and methodologies such as, proximate analysis, N2 adsorption–desorption isotherms, scanning electron microscope (SEM), Fourier transform infrared spectroscopy(FT-IR), X-ray Diffraction (XRD), X-ray photoe...