ABSTRACT The kinetics and mechanism of the aromatic nucleophilic substitution reactions of 2,6-bis(trifluoromethanesulfonyl)-4-nitroanisole with para-X-substituted anilines (X = OH, OMe, Me, H, F, I, Cl) were studied in MeOH-Me2SO mixtures and pure Me2SO at 25.0 °C. The second-order rate coefficients depend on the substitutent in aniline and give good Hammett and Brønsted correlations; a polar ...

a simple and reliable method for quick estimation of the dielectric constant of a binary solvent mixture is proposed. the validity of the proposed method has been tested for a broad range of binary solvent mixtures

In this article the behavior of tetrahydrofuran (THF) + 2-alkanol namely 2-propanol, 2-butanol, 2-pentanol, 2-hexanol and 2-heptanol binary mixtures through the density and viscosity measurements have been studied as a function of composition and within the temperature range of 293.15–313.15 K. The excess molar volume, isobaric thermal expansivity, partial molar volumes, and viscosity deviation...

Papain activity was studied in water-organic solvent mixtures using the fluorogenic substrate Dabcyl-Lys-Phe-Gly-Gly-Ala-Ala-Edans. The increase of organic solvent (MeOH, EtOH, iPrOH, TFE, MeCN, (MeO)2Et and DMF) concentration in the mixture caused a substantial decrease the initial rate of papain-catalyzed hydrolysis. Moreover, the number of papain active sites decreased with the increase of D...

Hybrid two-dimensional (2D) Raman-terahertz spectroscopy is used to measure the interactions between two solvents pair in binary CHBr3-MeOH mixture frequency range of 1-7 THz. Changes cross peak signature are monitored, originating from coupling an intramolecular bending mode CHBr3 collective intermolecular degrees freedom mixture. The appearance a new 2D spectrum measured for solvent with MeOH...

Densities, structural effects and viscosities of binary nonelectrolyte systems including nitrobenzene + 2-propanol, 2-butanol and 2-pentanol at temperatures (293.15 to 323.15) K and normal atmospheric pressure were measured using an Anton-Paar SVM 3000 stabinger viscometer. Excess molar volumes  and viscosity deviations Δη were calculated and correlated by the Redlich-Kister equation t...

In this study the intermolecular potential energies of some environment-friendly industrial HFC refrigerants were obtained through the inversion method which is based on the corresponding states principle. These potentials were later employed in calculation of transport properties (viscosity, diffusion, thermal conductivity and thermal diffusion factor) of some binary and ternary refrigerant mi...

This paper presents the experimental investigations conducted on a vertical closed loop pulsating heat pipe (VCLPHP) to evaluate the thermal performance. The values of thermal resistance and heat transfer coefficient obtained in the experimentation is used as evaluation parameters. The VCLPHP used has capillary tubes having an inner diameter of 2mm and outside diameter 3mm and bent into 5 turns...

The complexation reaction between hydroxyl ammonium (HONH3+ ) cation with 18-crown-6 (18C6) ligand was studied in dimethylsulfoxide – water (DMSO-H2O), methanol – water (MeOH-H2O) and dimethylformamid – methanol (DMF-MeOH), binary solutions at different temperatures using conductometric method. The obtained results show that the stoichiometry of t...

The formation of hydrates in oil and gas transmission pipelines can cause blockage inside them disrupt the normal flow. It may safety problems along with economic loss. To avoid these problems, it is necessary to have knowledge about hydrate formation. In this regard, liquid vapor equilibrium (HLVE) modeling prove be significance as predicts phenomenon accurately. Dickens Quinby-Hunt model used...