in this research, we have developed cheap recyclable and task-specific acidic ionic liquids (ails) 1-hydrogen-3-methylimidazolium hydrogen sulfate [hmim]hso4, 1-hydrogen-3-methylimidazolium chloride [hmim]cl, 2-pyrrolidonium hydrogensulfate [hnhp]hso4 and applied them in acid catalyzed synthesis of quinoxaline derivatives from 1,2-phenylendiamines and 1,2-dicarbonyl compounds. the products coul...

we optimized the geometries of the graphene and graphene with hydrogen using pw91vwn, pwcipl,mpwlyp, g96lyp, g96141.0-210.6-310, 6-31g*ievels of theory and compared our results with each other.we present the most important structural parameters determined for the addition of a hydrogen atom tographene and the outward movement of the carbon atom that is bonded to hydrogen is 0.48 a also wecalcul...

in this study, we have investigated radius dependence of hydrogen storage within armchair (n,n) single walled carbon nanotubes (swcnt) in a square arrays. to this aim, we have employed equilibrium molecular dynamics (md) simulation. our simulations results reveal that radius of carbon nanotubes are an important and influent factor in hydrogen distribution inside carbon nanotubes and consequentl...

In this paper, a solar based hydrogen production in the city of Tehran, the capital of Iran is simulated and the cost of produced hydrogen is evaluated. Local solar power profile is obtained using TRNSYS software for a typical parking station in Tehran. The generated electricity is used to supply power to a Proton Exchange Membrane (PEM) electrolyzer for hydrogen production. Dynamic nature of s...

full factorial experimental design (23) for the evaluation of slurry ethylene polymerization in the presence of an industrial ticl4/mgcl2 ziegler-natta catalyst was employed. the following parameters were used as independentvariables: al/ti molar ratio, reaction temperature and hydrogen partial pressure. the total polymerization pressure was 9 bar. catalyst activity, mfi (melt flow index) and m...

this is a report on the study of high melt flow, highly isotactic polypropylene homopolymer synthesized in liquid monomer using a fifth generation ziegler-natta catalytic system. at highest catalyst productivity, the response of thecatalyst to hydrogen as chain transfer is studied. melt flow rate is controlled by hydrogen as chain transfer from 0.4 to 300 g/10min with changing the amount of hyd...

A mixed proton–electron conducting perovskite was synthesized by liquid-citrate method and the corresponding membrane was prepared by pressing followed by sintering. The hydrogen permeability of BaCe0.9Yb0.1O3-δ was studied as a function of temperature and hydrogen partial pressure (PH2) gradient. Using 100% dry hydrogen at 1173 K, the hydrogen permeation rate of dense membranes (1.63 mm thick)...

odor emission is a common environmental problem in septic tank. the feasibility of using trickling filter to eliminate the malodorous gases from the septic tank was studied. a trickling filter is set up at the outlet of the waste gases of the septic tank, which was attached to the university's cafeteria. in this investigation, the trickling filter system was used, measuring the hydrogen sulfide...

introduction: nowadays, spermatogonial stem cells (sscs) cultivation has been used by many researchers as an effective tool for infertility treatments. oxidative conditions can be effective on cell proliferation and differentiation of these cells. so, the aim of this study was to establish oxidative stress model for antioxidant activity of some drugs investigation during sscs in vitro culture. ...