In this work, kinetics and thermodynamics of esterification reaction were studied. This research investigated the esterification reaction between methanol and acidified oil catalyzed by sulfonated cation exchange resin and proposed a new rate equation for consideration of kinetics of this reaction according to the Langmuir-Hinshelwood mechanism. Thermodynamics and kinetics parameters were calcu...

We studied laser-microdissection of standard and Langmuir-Blodgett (LB) nanotemplate protein crystals in glycerol solution. The time required for microdissection was significantly longer for LB-crystals as compared to standardcrystals which also more rapidly dissolve. Microfragmentation of lysozyme crystals was observed after extended solvent exposure. Synchrotron radiation nanobeam mapping all...

The removal ofxylenol orange from aqueous solution onto the coal ash was investigated at room temperature. The results show that the adsorption capacity of xylenol orange increased as the adsorption time increased and then equilibrium established after 30 min adsorption time. The results obtained revealed that the coal ash removed about 80 % of xylenol orange from the aqueous solution withi...

Adsorption equilibria were analyzed on the basis of general equilibrium constant expression for the development of fundamental adsorption equations (Freundlich, Langmuir, and BET) in connection with the establishment of a general approach towards physical interpretations of adsorption parameters. Theoretically it was proved that Freundlich plot analysis cannot be used to find useful parameters ...

Batch sorption study was performed using used black tea leaves (UBTL) as a low-cost adsorbent for the removal of lead (II) from aqueous solutions. Experiments were conducted as a function of contact time, initial metal ion concentration, solution pH and temperature. The sorption of Pb(II) on used tea leaves increases with increase of initial pH of solution upto a certain limit which corresponds...

The use of raw sawdust, RSD, of locust bean tree (Parkia biglobosa), a low-cost, locally available agroforestry waste as an adsorbent for removing a ternary mixture of heavy metals comprising of copper, lead and nickel (TMS) from aqueous solution was examined. Equilibrium data obtained from batch adsorption experiments were analysed with Langmuir, Freundlich and Temkin isotherm models, with Lan...

The efficiency of activated parthenium hysterophorous as an adsorbent for removing Pesticide mixture from water has been studied. Batch mode adsorption experiments have been conducted by varying pH, concentration, adsorbent dose and contact time. Pesticide removal was pH-dependent and found to be maximum at pH 2.0. The maximum removal of pesticides was achieved within 100 min after the start of...

Three isotherm models were used to describe adsorption equilibrium of a toxic chemical compound, phenol, onto a non porous adsorbent (Mediterranean Posidonia oceanica fibres) and a porous adsorbent, activated carbon prepared from Caribbean Vetiveria zizanoides roots. The adsorption characteristic parameters obtained were calculated using classical adsorption isotherm, i.e. the Langmuir (LI), Fr...