in this study, aluminum (al) matrix reinforced with micro-particles (30 µm) and nano-particles (50 nm) boron carbide (b4c) were used to prepare al-2.5%wt., b4c nano-composite and micro-composite, respectively, using mechanical alloying method. the mixed powders were mechanically milled at 5, 10, 15 and 20 hrs. the xrd results indicated that the crystallite sizes of both the micro-composite and ...

Palladium (II) coordination complexes catalyze the reaction of alcohols with ketones to yield ethers. During the catalytic cycle, the alcohol adds selectively to the β-carbon (anti-Markovnikov). In this work, mechanism and kinetics for the reaction of methanol with methyl vinyl ketone (MVK), being catalyzed by Pd, has been theoretically investigated in detail. Using quantum mechanical approach,...

in the present study, the influence of annealing temperature on mechanical properties and the microstructure of a high manganese austenitic steel (fe-30mn-4al-4si-0.5c) was investigated. x-ray diffractometry, optical and scanning electron microscopy, hardness and tensile tests were used to analyze the relationship between mechanical properties and microstructure after annealing process. the res...

Palladium (II) coordination complexes catalyze the reaction of alcohols with ketones to yield ethers. During the catalytic cycle, the alcohol adds selectively to the β-carbon (anti-Markovnikov). In this work, mechanism and kinetics for the reaction of methanol with methyl vinyl ketone (MVK), being catalyzed by Pd, has been theoretically investigated in detail. Using quantum mechanical approach,...

The effect of mechanical activation on structural changes and kinetics of carbothermic reduction of hematite with graphite was studied in this research. Hematite powder mixture with graphite (with stoichiometry ratio C/O=1) was milled for the time periods of zero to 50 hours, and the structural changes were studied using X ray diffraction (XRD). The effect of mechanical activation on the kineti...

An efficient solventless one-pot procedure for the synthesis of imidazolium-based ionic liquid under microwave irradiation is described in which 1-methylimidazole was modified by organosilane (3-chloropropyl triethoxysilane). This ionic liquid 1-methyl-3-[(triethoxysilyl)propyl]imidazolium chloride (TMICl) is immobilized on Mechanically activated Fly Ash (MFA) by co-condensation method to d...

a bionanocomposite film was developed by nanoclay incorporation to chitosan films, using a solution casting method and the effects of nanoclay concentration (0.5, 1.0, and 3% w/w) on the physical and mechanical properties of the chitosan films were evaluated. moreover, x-ray diffraction (xrd), scanning electron microscopy, and fourier transform infrared spectra (ftir) were used for studying mic...

this study was conducted to investigate the effects of applying methods andamount of ammonium polyphosphate (0, 2 and 4 wt%) on fire retardancy andmechanical properties of wood flour/polypropylene composites. the resultsshowed that addition of fire retardant improved the mechanical properties such astensile and flexural strengths and fire retardancy of composites. but by increasingof fire retar...

Isothermal redox kinetics of as-received Co3O4 (AC), 1 h ball milled Co3O4 (BC), and 1 h ball milled Co3O4-15wt.% Fe2O3 (BCF) was investigated at various temperatures (1130, 1100, 1070, and 1040 °C for reduction and 830, 860, and 890°C for re-oxidation) by thermogravimetric method. It was found that mechanic...