نتایج جستجو برای: methanol to olefins mto

تعداد نتایج: 10625400  

Due to its huge oil and gas reserves and access to open waters, Iran has considered the development of petrochemical products, including methanol, in the last decade; In such a way that the nominal production capacity of methanol in the country is about 9 million tons per year; According to investment plans in this industry until 1408, this number will arrive to 26 million tons yearly. due to t...

2017
Joris Goetze Florian Meirer Irina Yarulina Jorge Gascon Freek Kapteijn Javier Ruiz-Martínez Bert M. Weckhuysen

The nature and evolution of the hydrocarbon pool (HP) species during the Methanol-to-Olefins (MTO) process for three small-pore zeolite catalysts, with a different framework consisting of large cages interconnected by small eight-ring windows (CHA, DDR, and LEV) was studied at reaction temperatures between 350 and 450 °C using a combination of operando UV-vis spectroscopy and online gas chromat...

Journal: :Chemistry 2015
Chao Wang Xianfeng Yi Jun Xu Guodong Qi Pan Gao Weiyu Wang Yueying Chu Qiang Wang Ningdong Feng Xiaolong Liu Anmin Zheng Feng Deng

The methanol to olefins conversion over zeolite catalysts is a commercialized process to produce light olefins like ethene and propene but its mechanism is not well understood. We herein investigated the formation of ethene in the methanol to olefins reaction over the H-ZSM-5 zeolite. Three types of ethylcyclopentenyl carbocations, that is, the 1-methyl-3-ethylcyclopentenyl, the 1,4-dimethyl-3-...

Journal: :Chemical communications 2013
Liena Qin Hajime Hirao Jianrong Steve Zhou

A regioselective Heck reaction of aliphatic olefins and aryl bromides is realized at internal carbons of olefins. Methanol solvent promoted halide ionization from neutral arylpalladium halide complexes via hydrogen bonding, so as to create cationic aryl-Pd species for regioselective olefin insertion.

Journal: :Journal of the Mexican chemical society 2021

Abstract. SAPO-34 and ZnAPO-34 materials (Zn incorporated by isomorphic substitution in AlPO-34 material) were synthesized hydrothermal synthesis using triethylamine (TEA) as the structure directing agent (SDA). The presented both is to chabazite zeolite (CHA). However, they have different properties such textural (Z34 S34 a surface area of ​​485 603 m2/g, respectively), crystal sizes acid prop...

Journal: :Journal of the American Chemical Society 2007
Jason M Gonzales Robert Distasio Roy A Periana William A Goddard Jonas Oxgaard

Methylrhenium trioxide (MTO) has the rare ability to stoichiometrically generate methanol at room temperature with an external oxidant (H2O2) under basic conditions. In order to use this transformation as a model for nonredox oxidative C-O coupling, the mechanisms have been elucidated using density functional theory (DFT). Our studies show several possible reaction pathways to form methanol, wi...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه اراک - دانشکده علوم 1392

the history of plant’s used for mankind is as old as the start of humankind. initially, people used plants for their nutritional proposes but after the discovery of medicinal properties, this natural ?ora became a useful source of disease cure and health improvement across various human communities. berberis vulgaris is one of the medicinal plants used in iranian traditional medicine. berberis ...

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