Magnetically separable gold-nanoparticle catalyst was prepared, and it showed excellent activity for chemoselective reduction of nitroarenes with hydrosilanes.

Iron containing nanoparticles are found to spontaneously form on hydroxylated SiO2 substrates when immersed in a freshly mixed aqueous solution of FeCl3 and hydroxylamine. Upon calcination, a submonolayer of uniformly distributed iron oxide nanoparticles can be derived and used to catalyze the growth of single-walled carbon nanotubes by chemical vapor deposition. This simple method affords clea...

This work examines the recent developments in non-traditional catalyst-assisted chemical vapour deposition of carbon nanotubes (CNTs) with a view to determining the essential role of the catalyst in nanotube growth. A brief overview of the techniques reliant on the structural reorganization of carbon to form CNTs is provided. Additionally, CNT synthesis methods based upon ceramic, noble metal, ...

An environmentally friendly ("green"), H2-generation system was developed that involved hydrolytic oxidation of inexpensive organosilanes as hydrogen storage materials with newly developed heterogeneous gold nanoparticle catalysts. The gold catalyst functioned well at ambient temperature under aerobic conditions, providing efficient production of pure H2. The newly developed size-selective gold...

Dye photodegradation using ozone and Nickel ferrite nanoparticle (NFN) as a photocatalyst was studied. The catalyst was synthesized and characterized by FT-IR, SEM and XRD. Textile dyes including Remazol Red RB (RRRB) and Direct Green B (DGB) were degraded as model compounds. Dye degradation was investigated using UV–Vis and ion chromatography (IC) analyses. The effect of catalyst dosage, pH, s...

The adsorption properties of CO and H2 on iron-based catalyst with addition of Zr and Ni were investigated using temperature programmed desorption process. It was found that on the carburized iron-based catalysts, molecular state and dissociative state CO existed together. The addition of Zr was preferential for the molecular state adsorption of CO on iron-based catalyst and the presence of Ni ...

The oxidation of ammonia to nitrogen by selective catalytic oxidation (NH3-SCO) over a bimetallic CuO/CeO2 nanoparticle catalyst at temperatures between 423 and 673K. A bimetallic CuO/CeO2 nanoparticle catalyst was prepared by co-precipitation method at molar ratio of 6:4. This study also considers how the concentration of influent NH3 (C0 = 800 ppm), the space velocity (GHSV = 92000/hr), the r...

A copper(II)-oxide-based exhaust catalyst exhibits better activity than Pt- and Rh-nanoparticle catalysts in NO remediation at 175 °C. Following theoretical design, the CuO catalyst is rationally prepared; CuO nanoplates bearing a maximized amount of the active {001} facet are arranged in interleaved layers. A field test using a commercial gasoline engine demonstrates the ability of the catalys...

Due to the feasibility of ethanol production in the United States, ethanol has become more attractive as a fuel source and a possible energy carrier within the hydrogen economy. Ethanol can be stored easily in liquid form, and can be internally pre-formed prior to usage in low temperature (200 o C – 400 o C) solid acid and polymer electrolyte membrane fuel cells. However, complete electrochemic...