Characterization of liquid-liquid equilibrium (LLE) in system containing ionic liquids (ILs) is important in evaluating ILs as candidates for replacing traditional extraction and separation solvents. Though an increasing amount of experimental LLE data is becoming available, comprehensive coverage of ternary liquid-phase behavior via experimental observation is impossible. Therefore, it is impo...

The effect of magnetic field on the liquid-liquid equilibrium of two ternary systems (water + acetic acid + butyl acetate and water + acetic acid + dimethyl succinate) at 298.15 K under atmospheric pressure was investigated. The results obtained show that the strength of the magnetic field (0.02 T) affects the solubility of acetic acid in the used organic solvents. Distribution coefficients and...

In this work we use adjusted parameters obtained with Simulated Annealing and those from Dechema Collection [1] for the NRTL model, in order to analyze their effect in the design, optimization, and control of homogeneous azeotropic distillation columns. For the design of the azeotropic sequences we use short design methodologies [2, 3], while a multiobjective genetic algorithm with constraints ...

In order to reduce global CO2 emissions, capture based on absorption in an amine/water mixture is established method. To develop such processes, correct physicochemical properties like densities and viscosities are important.The first objective of this work explore mathematical correlations for fitting viscosity data aqueous Monoethanolamine (MEA) Methyldiethanolamine (MDEA). A second evaluate ...

In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (electrolyte Non-Random Two-Liquid e-NRTL and Mean Spherical Approximation-Non-Random Two-Liquid MSA-NRTL), association between ions of opposit...

thermodynamic restrictions and simultaneous effects of operational conditions on the homogeneous rhodium-catalyzed carbonylation of methanol are studied in this line of research. it is shown that the general nrtl-virial model can be appropriated to study thermodynamics of the carbonylation. it is obtained that the reaction is kinetically and thermodynamically reasonable at temperatures above 42...