a new method for the synthesis of nano zero-valent iron (nzvi) was developed in the present study.ultrasonic waves, as a novel method, were used to synthesize the nanoparticles. the morphologyand surface compositions of the particles were characterized by using fesem, xrd, bet, andparticle size analyzer. the synthesized nanoparticles were then utilized as a fenton-like catalyst todegrade of hyd...

Superparamagnetism is a phenomenon caused by quantum effects in magnetic nanomaterials. Zero-valent metals with diameters below 5 nm have been suggested as superior alternatives to superparamagnetic metal oxides, having greater superspin magnitudes and lower levels of magnetic disorder. However, synthesis of such nanometals has been hindered by their chemical instability. Here we present a meth...

Zero-valent iron (ZVI) and green rusts can be used as reductants to convert chromium from soluble, highly toxic Cr(VI) to insoluble Cr(III). This study compared the reduction rates of Cr(VI) by ZVI and two carbonate green rust phases in alkaline/hyperalkaline solutions. Batch experiments were carried out with synthetic chromate solutions at pH 7.7-12.3 and a chromite ore processing residue (COP...

In this study, nanoscale zero-valent iron nanoparticles (NZVIs) were coated with silica and polydopamine using a two-step process. The coated nanoparticles were applied as adsorbents for removal of two common polycyclic aromatic hydrocarbons pollutants, phenanthrene (PHE) and anthracene (ANT) from aqueous system. Adsorption kinetics followed a pseudo-second-order model. Isotherms and thermodyna...

iron (in zero-valent and oxide forms) is used to remove numerous organic and inorganic contaminants in environment. however, there are few reports, especially in nano scale, on the remediation of heavy metals contaminated soils using zero-valent iron in the literature. in this study, the effect of iron on the availability of heavy metals was evaluated in a calcareous soil spiked with cadmium, z...

Dichloroethane is a raw material used for the manufacture of vinyl chloride monomer (VCM) and therefore has very often been detected as a contaminant in the groundwater nearby the VCM manufacturing plant. Zero-valent iron is capable of degrading a wide array of chlorinated contaminants in groundwater such as trichloroethylene, vinyl chloride, carbon tetrachloride, and tetrachloroethane. However...

In recent years, there has been an increasing use of engineered magnetic nanoparticles for remediation and water treatments, leading to elevated public concerns. To this end, it is necessary to enhance the understanding of how these magnetic nanoparticles react with contaminants and interact with the surrounding environment during applications. This review aims to provide a holistic overview of...