in this thesis, phosphorus ylides [phbppy], [no2bppy] and [brbppy] have been synthesized through the formation of phosphonium salt and dihydrogenation, followed by the reaction of pd(oac)2 and the orthopalladated dinuclear complexes [pd(?-cl)(phbppy)]2, [pd(?-cl)(no2bppy)]2 and [pd(?-cl)(brbppy)]2 have been produced. the reaction of dinuclear complexes and bidentate ligands [l = bipy (2,2-bipyr...

in recent years many researchers have been focused on interaction of small molecules with dna. dna is generally the primary intracellular of anticancer drugs, so the interaction between small molecules and dna can cause dna damage in cancer cells, blocking the division of cancer cells and resulting in cell death. the flavonoids are a large group of polyphenolic natural products that are widely ...

in this thesis, we exploit a simple and suitable method for immobilization of copper(ii) complex of 4?-phenyl-terpyridine on activated multi-walled carbon nanotubes [amwcnts-o-cu(ii)-phtpy]. this nanostructure was characterized by various physico-chemical techniques. to ensure the efficiency and fidelity of copper species, the implementation of three-component strategies in click-chemistry all...

in this study, scour of mashkid bridge pier located in mashkid river of saravan county has been studied and to measure the scour rate, the numerical model hec-ras 4.0 has been used. upon selection of mashkid river as the case study and whereas the studied zone is important with respect to the climatic conditions and showery monsoon raining and flowing the great and destructive floodwaters, ther...

seismic retrofit strategies have been developed in the past few decades following the introduction of new seismic provisions and the availability of advanced materials and methods. it can be observed that new approaches to deal with more lateral forces are more innovative and more energy absorbent. in line with this, there is a growing trend toward the use of steel shear walls as a system with ...

in the first part of this thesis we explored wetting and its dynamics for small droplets. first, we showed how a simple feature of water droplets on a surface, i.e. laplace pressure, can be exploited to build a micropump. we investigated capillary pumping in microchannels both experimentally and numerically. putting two droplets of different sizes at the in/outlet of a microchannel, will ge...

In order to investigate mineral manganese forms and their relations with plant responses, 22 soil samples from Fars province (0-20 cm) were in a greenhouse experiment filled in 3 liter pots, and soybean (Glycine max (L.) merr.,CV.Williams) was grown for 7 weeks. Chemical forms of manganese were determined in soils by warden and Reisenauer sequential extraction method (readily soluble, weakly ad...

Information about forms of zinc (Zn) is important for the evaluation of its status in soil and also understanding of the soil fertility and chemistry. To obtain such information, amounts and distribution of Zn in different fractions of 20 soil samples of Tehran province, Iran were determined by sequential extraction method and their relationships with each other and with soil characteristics we...

Information about forms of zinc (Zn) is important for the evaluation of its status in soil and also understanding of the soil fertility and chemistry. To obtain such information, amounts and distribution of Zn in different fractions of 20 soil samples of Tehran province, Iran were determined by sequential extraction method and their relationships with each other and with soil characteristics we...

In order to investigate mineral manganese forms and their relations with plant responses, 22 soil samples from Fars province (0-20 cm) were in a greenhouse experiment filled in 3 liter pots, and soybean (Glycine max (L.) merr.,CV.Williams) was grown for 7 weeks. Chemical forms of manganese were determined in soils by warden and Reisenauer sequential extraction method (readily soluble, weakly ad...