Measuring electrochemical activities of nanomaterials is critical for creating novel catalysts, for developing ultrasensitive sensors, and for understanding fundamental nanoelectrochemistry. However, traditional electrochemical methods measure a large number of nanoparticles, which wash out the properties of individual nanoparticles. We report here a study of transient electrochemical oxidation...

In this work, we reported a facile one-pot hydrothermal method to synthesize MnPO4·H2O nanowire/graphene oxide composite material with coated graphene oxide. Transmission electron microscopy and scanning electron microscope were employed to study its morphology information, and X-ray diffraction was used to study the phase and structure of the material. Additionally, X-ray photoelectron spectro...

A new electrochemical model has been carefully established to explain the carbonation behavior of cement mortar, and the model has been validated by the experimental results. In fact, it is shown by this study that the electrochemical impedance behavior of mortars varies in the process of carbonation. With the cement/sand ratio reduced, the carbonation rate reveals more remarkable. The carbonat...

Recently, we introduced a new electrochemical imaging technique called fluorescence-enabled electrochemical microscopy (FFEM). The central idea of FEEM is that a closed bipolar electrode is utilized to electrically couple a redox reaction of interest to a complementary fluorogenic reaction converting an electrochemical signal into a fluorescent signal. This simple strategy enables one to use fl...

Neurons release neurotransmitters in a process called exocytosis, wherein packets of transmitter molecules are released from the cells upon stimulation. Adrenal chromaffin cells, which also undergo exocytosis, constitute a model system for neuronal release. Quantal release of adrenaline from chromaffin cells can be measured using the electrochemical technique of amperometry, historically employ...

The work described in this thesis has the focus on the development of new analytical tools to study processes related to cellular secretion (exocytosis) in cell models. Four novel techniques were developed, allowing new ways to study processes related to exocytosis, and gain previously unattainable knowledge. The methods were applied to single cells as well as to populations of cells in culture...

Electrochemical micromachining (ECMM) is a non-conventional manufacturing method suitable for the production of microsized components on a wide range of conductive materials. ECMM improves dimensional accuracy and simplifies tool design for machining hard, high strength, heat resistant, and conductive materials into complex shapes. Extremely small interelectrode gaps of the order of few microns...