the reduction mechanism of molybdenum-methyl thymol blue (mtb)-chlorate system has been investigated in water on a mercury electrode. as this system is very sensitive for ultratrace determination of molybdenum, the actual mechanism involved was studied. electrochemical techniques, including dc tast polarography and cyclic voltammetry were employed. it is shown that, the cathodic wave of molybde...

a systematic study on the electrochemical behavior of the s-derivatives of 2-amino cyclopentene-1-dithiocarboxylic acid (acda) has been carried out in aqueous ethanolic solutions by means of polarography, coulometry and voltammetry. all the compounds studied exhibited a well defined anodic wave corresponding to a diffusion controlled process. controlled potential coulometry gave n=1 per mole fo...

the aim of this study was to determine the feasibility of coupling an electrochemical process with a biological treatment in order to degrade phosmet, an organophosphorous pesticide. the absence of biodegradability of phosmet by pseudomonas fluorescens and activated sludge was verified in our operational conditions. so, a conventional biological treatment is not appropriate for phosmet polluted...

the aim of this study was to determine the feasibility of coupling an electrochemical process with a biological treatment in order to degrade phosmet, an organophosphorous pesticide. the absence of biodegradability of phosmet by pseudomonas fluorescens and activated sludge was verified in our operational conditions. so, a conventional biological treatment is not appropriate for phosmet polluted...

Simultaneous acquisition of in vivo electrophysiological and neurochemical information is essential for understanding how endogenous neurochemicals modulate the dynamics of brain activity. However, up to now such a task has rarely been accomplished due to the major technical challenge of operating two independent recording systems simultaneously in real-time. Here we propose a simpler solution ...

the applications of electrochemical machining are increasing because of increasing requests of industries for materials with high strengh and high hardness. regular ecm uses a tool with spicified profile shape that is similar to final shape of workpiece. in this reasearch a nozzle that delivers electrolyte to the machining gap is used for machining cylinderical workpieces. by moving the electro...

In the course of a series of investigations on the physical chemistry of hemoglobin now being carried on in the Laboratory of Physical Chemistry of the Harvard Medical School, Dr. E. J. Cohn and Dr. R. M. Ferry discovered certain abnormalities in the behavior of a hydrogen electrode immersed in solutions of hemoglobin and oxyhemoglobin. On studying the matter further they found that any inert e...