This discussion paper is/has been under review for the journal Atmospheric Chemistry and Physics (ACP). Please refer to the corresponding final paper in ACP if available. Abstract The effect of dry and wet deposition of semi-volatile organic compounds (SVOC) in the gas-phase on the concentrations of secondary organic aerosol (SOA) is reassessed using recently derived water solubility informatio...

A series of hydroxyl-group containing polyimides (HPIs) were prepared in order to investigate the structure-gas permeation property relationship. Each polymer membrane had structural characteristics that varied according to the dianhydride monomers. The imidization processes were monitored using spectroscopic and thermog-ravimetric analyses. The single gas permeability of He, H 2 , CO 2 , O 2 ,...

A mathematical model of a subject breathing from a circle system has been used to follow the course of anaesthetic uptake during the simulated administration of 60% nitrous oxide, 2% halothane and 2% methoxyflurane, under non-rebreathing conditions and with fresh gas flows to the circle system of between 8 and 0.25 litre min-1. Compared with the non-rebreathing state, the use of a circle system...

Gas hydrate can precipitate in pore space of marine sediment when gas concentrations exceed solubility conditions within a gas hydrate stability zone (GHSZ). Here we present analytical expressions that relate the top of the GHSZ and the amount of gas hydrate within the GHSZ to the depth of the sulfate-methane transition (SMT). The expressions are strictly valid for steady-state systems in which...

The present work reports on the gas transport behavior of mixed matrix membranes (MMM) which were prepared from multi-walled carbon nanotubes (MWCNTs) and dispersed within polymers of intrinsic microporosity (PIM-1) matrix. The MWCNTs were chemically functionalized with poly(ethylene glycol) (PEG) for a better dispersion in the polymer matrix. MMM-incorporating functionalized MWCNTs (f-MWCNTs) ...

We evaluated the effect of starvation on anaesthetic solubility in tissues involved in lipid transport (blood) or metabolism (liver) and in a tissue not involved in either (brain). The liver/gas partition coefficients of isoflurane, enflurane, halothane and methoxyflurane in rats increased by 15-20% after 6 h of starvation and reached a maximum increase of 35-42% after 24 h of starvation. After...

Work in 2012-2013 focused on studying gas permeability, diffusivity and solubility of polyimides and thermally rearranged (TR) polymers based on 3,3’-dihydroxy-4,4’diaminobiphenyl (HAB) and 2,2’-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA). To determine the effect of temperature on gas sorption, we studied H2 sorption in the HAB-6FDA polyimide and 3 partially converted HAB-6FD...

We present an approach to calculate the atomic bulk solubility in binary alloys based on the statistical-thermodynamic theory of dilute lattice gas. The model considers all the appropriate ground states of the alloy and results in a simple Arrhenius-type temperature dependence determined by a ‘‘low-solubility formation enthalpy”. This quantity, directly obtainable from first principles, is defi...

The present interest in the physiology of inert gases makes desirable a more accurate and reproducible method for determining the inert gas content of biological fluids than is currently available (2). This communication describes such a method. The method has been tested on water and used to determine the solubility of the inert gas of air in human urines of different solute concentrations at ...