Intermetallide phase formation was studied in a powdered Fe–Al system under layer by layer laser cladding with the aim of fabricating the gradient of properties by means of changing the Fe–Al concentration ratio in the powder mixture from layer to layer. The relationships between the laser cladding parameters and the intermetallic phase structures in the consecutively cladded layers were determ...

Intermetallic compounds containing transition metals and sp elements often form a gap at the Fermi energy due to hybridization. This gap can be exploited for applications, making these compounds the subject of intense study. For example, intermetallic semiconductors are attractive for use in thermoelectric devices due to their typically small gaps and large Seebeck coefficients (ex. ZrNiSn) [1]...

Although metal-metal bonding is important in the chemistry of both solid-state intermetallic compounds and molecular species, the study of this bonding is limited by the compounds available and it is rarely possible to identify connections between these two areas. In this study, molecular intermetalloids [Ln(ReCp(2))(3)] (Ln = Sm, Lu and La) have been synthesized that contain lanthanoid metals ...

New Mg-3Zn-2Ca magnesium alloy was prepared using different processing techniques: gravity casting as well as squeeze casting in liquid and semisolid states. Materials were further thermally treated; thermal treatment of the gravity cast alloy was additionally combined with the equal channel angular pressing (ECAP). Alloy processed by the squeeze casting in liquid as well as in semisolid state ...

The results of a thorough structural study of crystalline intermetallic compounds within the Al-Li-(Cu,Mg,Zn) system are given. Characteristic morphologies of these ternary or quaternary phases are exhibited by concentrated alloys or large single crystals. Typical X-ray powder diffraction data, selected area electron diffraction patterns and high resolution electron microscopy images are shown,...

Intrinsically chiral surfaces of intermetallic compounds are shown to be novel materials for enantioselective processes. Their advantage is the significantly higher thermal and chemical stability, and therefore their extended application range for catalyzed chiral reactions compared to surfaces templated with chiral molecular modifiers or auxiliaries. On the Pd1 -terminated PdGa(111) surface, r...

The enhanced stability and modified electronic structure of intermetallic compounds provide discovery of superior catalysts for chemical conversions with high activity, selectivity, and stability. We find that the intermetallic NaAu2 is an active catalyst for CO oxidation at low temperatures. From density functional theory calculations, a reaction mechanism is suggested to explain the observed ...

The compositions and structures of thermodynamically stable or metastable precipitations in binary Mg-X (X=Sn, Y, Sc, Ag) alloys are predicted using ab-initio evolutionary algorithm. The geometry optimizations of the predicted intermetallic compounds are carried out in the framework of density functional theory (DFT) [1]. A complete list of the optimized crystallographic information (in cif for...

The recent work of the authors' group in the field of KEMS studies of intermetallic gaseous molecules is reviewed. Examples are given of systems such as intragroup 14 diatomic molecules, -triand tetratomic species in the SiSn systems, and diatomic species containing Group 11 elements. Special attention is given to species containing heavy metals, where relativistic effects can play an important...