Characterization of mesoporous adsorbents is traditionally performed in terms of the pore size distribution with bulk methods like physisorption and mercury intrusion. But their application relies on assumptions regarding the basic pore geometry. Although novel tools have enabled the quantitative interpretation of physisorption data for adsorbents having a well-defined pore structure the analys...

We computationally investigate cross-property correlations linking fluid permeability to conductive properties in sedimentary rock for a number of pore size parameters based on three-dimensional digitized rock images. In particular, we focus on correlations based on the pore volume-to-surface-area ratio (V(p)/S), a critical channel diameter (c) associated with mercury porosimetry measurements, ...

Development of microporous materials with hierarchical structures of both micro/mesopores leads to molecular transport at nanometer length scales. For novel microporous materials including three-dimensionally ordered mesoporous imprinted (3DOm-i) zeolites and zeolite nanosheets, particle dimensions are below 35 nm resulting in surface-dominated structures. At the same time, the existence of sur...

Pontonema golfonuevensis sp. nov. from Chubut Province, Argentina is described and a description of the male of Pontonema incisum Wieser, 1953 from Chubut and Santa Cruz Provinces is provided. Pontonema golfonuevensis sp. nov. is characterized by having the slender sub-ventral teeth 25 µm long located at 24 % of stoma length, a short, broad dorsal tooth at 60 % of stoma length, excretory pore o...

The chromatin structures of a variety of plasmids and plasmid constructions, transiently transfected into mouse Ltk- cells using the DEAE-dextran procedure, were studied by micrococcal nuclease digestion of nuclei and Southern hybridization. Although regularly arranged nucleosome-like particles clearly were formed on the transfected DNA, the nucleosome ladders, in some cases with 13-14 bands, w...

Submitted for the MAR08 Meeting of The American Physical Society Computer simulations of polymer reversal inside a pore LEI HUANG, DMITRII E. MAKAROV, University of Texas at Austin — Translocation of biopolymers through pores is implicated in many biological phenomena. Confinement within pores often breaks ergodicity on biological time scales by creating large entropic barriers to rearrangement...

in the present study, the effect of porosity on the cathode microstructure (50:50 wt. % lsm: ysz) of a solid oxide fuel cell (sofc) has been examined. a 3-d finite element method for mixed ionic and electronic conducting cathodes (miec) is presented to study the effects of porosity on cell performance. each microstructure was realized using the monte carlo approach with the isotropic type of gr...

Molecular Dynamics simulations of a coarse-grained bead-spring model of flexible macromolecules tethered with one end to the surface of a cylindrical pore are presented. Chain length N and grafting density σ are varied over a wide range and the crossover from “mushroom” to “brush” behavior is studied for three pore diameters. The monomer density profile and the distribution of the free chain en...

Post-synthetic modification (PSM) of the interpenetrated diamondoid metal–organic framework (Me2NH2)[In(BDC-NH2)2] (BDC-NH2=aminobenzenedicarboxylate) SHF-61 proceeds quantitatively in a single-crystal-to-single-crystal manner to yield acetamide derivative (Me2NH2)[In(BDC-NHC(O)Me)2] SHF-62. Continuous breathing behaviour during activation/desolvation is retained upon PSM, but pore closing now ...