A built experimental set-up was employed for the estimation of the solid-liquid equilibria of alternative refrigerants systems. The behavior of carbon dioxide + 1,3,3,3-tetrafluoropropene (CO2 + R1234ze(E)) was measured down to temperatures of 160.0 K. The results obtained for the mixtures were interpreted by means of the Schröder equation.

liquid-liquid equilibria for the (water + lactic acid + benzyl alcohol or p-xylene) ternary systems were investigated at atmospheric pressure and in the temperature range from 298.15-318.15 k. the studied systems exhibit two types of liquid-liquid equilibrium (lle) behavior. the system consisting of benzyl alcohol displays type-1 lle behavior, while a type-2 behavior is exhibited by the other s...

Liquid-liquid equilibria for the (water + lactic acid + benzyl alcohol or p-xylene) ternary systems were investigated at atmospheric pressure and in the temperature range from 298.15-318.15 K. The studied systems exhibit two types of liquid-liquid equilibrium (LLE) behavior. The system consisting of benzyl alcohol displays type-1 LLE behavior, while a type-2 behavior is exhibited by th...

Based on Gibbs-Duhem law and using UNIFAC-FV computer algorithm, the activity of polymer component in polymer-solvent systems is determined. The variation of activity of components with concentration at different temperatures are used to find the equilibrium concentration, UCST, and LCST for the systems. Also by generalization of the method, Gel-Liquid equilibrium is studied in some three c...

The solid?liquid phase equilibria (SLE) and densities of H2O?NaCl? ?MnCl2?Mn(H2PO2)2 quaternary system H2O?NaCl?MnCl2 H2O? ternary systems were investigated at 323.15 K by the isothermal solution saturation method. analyses liquid solid phases used to determine composition using Schreinemakers graphic contain one invariant point, two curves crystallization regions. In system, there is three are...

The global phase diagram ~i.e., vapor–liquid and fluid–solid equilibrium! of two-center Lennard-Jones ~2CLJ! model molecules of bond length L5s has been determined by computer simulation. The vapor–liquid equilibrium conditions are obtained using the Gibbs ensemble Monte Carlo method and by performing isobaric-isothermal NPT calculations at zero pressure. In the case of the solid phase, two clo...

The effect of three-body interactions on the solid-liquid phase boundaries of argon, krypton, and xenon is investigated via a novel technique that combines both nonequilibrium and equilibrium molecular dynamics. The simulations involve the evaluation of two- and three-body forces using accurate two-body and three-body intermolecular potentials. The effect of three-body interactions is to substa...