the simplified perturbed chain statistical associating fluid theory (spc-saft) equation of state (eos) was proposed to describe the thermodynamic properties of pure ionic liquids (ils). a set of spc-saft parameters for 2 ils was obtained by fitting the experimental liquid densities data over a wide range of temperature at atmospheric pressure. good agreement with experimental density data was o...

in this work, we consider each normal alkane as a hypothetical mixtureof methyland methylene groups, in which the interaction potential of each pair is assumed to be the average effective pair potential. then, the lir equation of state (eos) is extended for such a hypothetical mixture. also, three basic compounds, namely, propane, n-butane and cyclohexane, are used to obtain the contribution of...

An optical system has been redesigned and used to measure detonation velocity as a function of condensed explosive density for RDX, HMX, PETN. These measurements are then used to determine and fine tune parameters appearing in the BKW (Beker-Kistiakowsky-Wilson) equation of state for gases at extremely high pressures. Steady state form of conservation equations along with the BKW state equation...

We developed an equation of state (EOS) by Ihm, Song, and Mason (ISM) for polar fluids. The model consists of four parameters, namely, the second virial coefficient, an effective van der Waals co-volume, a scaling factor, and the reduced dipole moment. The second virial coefficient is calculated from a correlation that uses the heat of vaporization, and the liquid density at the normal boiling ...

calculate some thermodynamic properties of molten polymers including specific volume and isothermal compressibility (S.M. Hoseini, Physical Chemistry & Electrochemistry, 2 (2014) 56-65). This work extended that EOS to predict the volumetric properties of some molten ethylene copolymers including ethylene/1-octene, ethylene/1-butene (xethylene equal to 0.8543 and 0.563), ethylene/propene. The ab...

The present work is the successful extension of an improved equation of state (EOS) to refrigerant fluids. The objective is the prediction of isothermal and saturated liquid densities of refrigerants. Two temperature-independent parameters appearing in the modified EOS are closely related to critical point properties of refrigerant fluids. Our results showed that, the proposed EOS can predict w...

Landauer’s principle is applied to information in the universe. Once stars began forming there was a constant information energy density as the increasing proportion of matter at high stellar temperatures exactly compensated for the expanding universe. The information equation of state was close to the dark energy value, w = -1, for a wide range of redshifts, 10> z >0.8, over one half of cosmic...

alkanolamine solutions such as 2-amino-2-methyl-1-propanol (amp) are widely used in chemical industries for the removal of acid gases such as co2 and h2s. in this work, the density of co2, amp, water, and amp solutions using the goharshadi–morsali–abbaspour equation of state “gma eos” in the extended 50-degree range of temperatures (313.06-362.65 k) and pressures (0.5-40 mpa) was calculated. th...

solubility of high molecular weight n-paraffins in supercritical carbon dioxide has been a matter of interest to many researchers. however, not sufficient solubility experimental data are available although the methods by which the experimental data are obtained have many varieties. utilizing cubic equations of state is an effective method for solubility prediction of n-paraffins in supercritic...