The oxidation of aniline to azobenzene was conducted in the presence of either monolayer graphene (EG) or graphene-oxide-like surface, such as GOx, under ultra-high vacuum conditions maintaining a 365-nm UV light exposure to enhance the oxidation reaction. The surface-bound products were investigated using micro Raman spectroscopy, high-resolution photoemission spectroscopy, and work function m...

Increasing numbers of workers in industry are working a novel or unusual 12-hr workshift in which the exposure time is longer and the recovery period is shorter than for a standard 8-hr workshift. Experiments were conducted to examine the effects of altering the exposure schedule of rats from 8 hr/day for 5 days to 12 hr/day for 4 days on the toxicity resulting from the inhalation of aniline at...

The synthesis and properties of new monoazo dyes derived from the diazonium salts of paminobenzoic acid, 3-trifluoromethyl aniline , 4-trifluoromethyl aniline are considered .Theprepared compounds were characterized by UV-Visible , FT-IR and H NMR spectroscopictechniques . The effect of varying solvent upon the absorption ability of p-amino benzoic acidcoupled with 4,4 —diethyl aniline , anilin...

This study was carried out in two stages. In the first stage; 2-oxo-2-phenylethyl-2-aminobenzoate (OPA) compound, which an aniline derivative, synthesized by starting appropriate components. Then, poly(OPA) obtained via chemical polymerization of OPA presence ammonium peroxydisulfate (APS) as initiator and DMF solvent. Poly(OPA)/Bentonite (BNT) nanocomposite effectively dispersing inorganic nan...

Six nonlinear, optical chromophores, Z1–Z6, based on the bis(N,N-diethyl)aniline-derived donor and thiolated isophorone bridge, were designed synthesized. The was applied in a chromophore with as an electron bridge for first time. In particular, parts of chromophores Z2–Z6 modified different functional groups, including tert-butyltrimethylsilane tert-butyl(methyl)diphenylsilane derivative: 1,3-...

Comprehensive studies of the molecular and electronic structures, vibrational frequencies, and infrared and Raman intensities of the aniline radical cation, C6H5NH2 1 have been performed by using the unrestricted density functional ~UB3LYP! and second-order Møller–Plesset ~UMP2! methods with the extended 6-31111G~df,pd! basis set. For comparison, analogous calculations were carried out for the ...

The chemotherapeutic agent known as 5-fluorouracil (5-FU) is an artificial fluoropyrimidine antimetabolite that has been widely used for its antineoplastic properties. Cocrystals of with five different Schiff bases (benzylidene-urea (BU), benzylidene-aniline (BA), salicylidene-aniline (SA), salicylidene-phenylhydrazine (SPH), and para-hydroxy benzylideneaniline (HBA)) are reported in this study...