The aim of this work was the evaluation of the catalytic steam reforming of a gaseous fuel obtained by steam biomass gasification to convert topping atmosphere residue (TAR) and CH4 and to produce pure H2 by means of a CO2 sorbent. This experimental work deals with the demonstration of the practical feasibility of such concepts, using a real woodgas obtained from fluidized bed steam gasificatio...

Improvements in diesel engine aftertreatment technology are needed to meet future environmental quality goals. Systems using recently developed compact plasmatron fuel converters in conjunction with aftertreatment catalysts could provide new opportunities for obtaining significant pollution reductions. Use of compact plasmatron reformers to produce hydrogen-rich gas for the regeneration of NOx ...

Pyrolytic graphite particles modified with hydrogenase and an NAD(+)/NADH cycling enzyme provide a modular heterogeneous catalyst system for regeneration of oxidised or reduced nicotinamide cofactors using H(2) and H(+) as electron source or sink. Particles can be tuned for cofactor supply under different conditions by appropriate choice of hydrogenase.

An L-proline based supramolecular hydrogel is used as an efficient heterogeneous organocatalyst for the direct aldol reaction with high stereoselectivity (up to 90% ee) and recyclability (up to 3 runs). The reversible nature of this self-assembled supramolecular system allows for easy recovery and regeneration of the catalyst.

It is well known that well-defined polyacrylonitrile (PAN) with high molecular weight (Mw > 106 g ̈mol ́1) is an excellent precursor for high performance carbon fiber. In this work, a strategy for initiators for a continuous activator regeneration atom transfer radical polymerization (ICAR ATRP) system for acrylonitrile (AN) was firstly established by using CuCl2 ̈ 2H2O as the catalyst and 2,21-az...

The presence of biogenic or process-derived impurities poses a major problem on the efficient catalytic hydrogenation of biomass-derived levulinic acid to γ-valerolactone; hence, studies on their influence on catalyst stability are now required. Herein, the influence of sulfuric acid as feed impurity on the performance of Ru-based heterogeneous catalysts, including Ru/ZrO2 and mono- and bimetal...

The catalyst regeneration is still a challenge to make the ethanol steam reforming (ESR) process feasible for sustainable H2 production. NiAl2O4 spinel derived catalysts are highly active and selective ESR, but they require avoiding irreversible deactivation ensure their regeneration. Their stability depends on structure, herein we report different Ni/Al2O3-NiAl2O4 obtained upon reduction of at...

When dihydroxylated benzenes are oxidized, during the initial minutes there is an elevated consumption of dissolved oxygen (DO), achieving a minimum value. Next, DO increases following second order kinetics, whose reaction rates depend on the nature of the compounds. In this stage, occurs the catalyst regeneration that releases oxygen, being possible to establish a relation-ship between the rat...

Heavy-duty over-the-road trucks require periodic active diesel particulate filter regeneration to clean the filter of stored particulate matter. These events require sustained temperatures between 500 and 600°C to complete the regeneration process. Engine operation during typical 65mile/h highway cruise conditions (1200 rpm/7.6 bar) results in temperatures of approximately 350°C, and can reach ...