We report the results from an operando XRD-CT study of a working catalytic membrane reactor for the oxidative coupling of methane. These results reveal the importance of the evolving solid state chemistry during catalytic reaction, particularly the chemical interaction between the catalyst and the oxygen transport membrane.

background: catalytic ozonation has recently been applied as a new method of contaminant removal from water and wastewater. in this study, copper coated pumice and zeolite were used to catalyze the ozonation of phenol as a target pollutant from aqueous solutions. methods: the pumice and zeolite stone were modified by cuso 4 (1n). modified pumice and zeolite were characterized by adsorption/deso...

A co-impregnation method was applied to the Ni/Zr-HMS/HZSM-5 catalyst (with various amounts of zirconium) during the hydrogenation of benzene. The physicochemical properties of the prepared nickel catalyst were characterized using X - ray diffraction, X - ray fluorescence, Fourier transform infrared spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy, temperature-programmed desor...

The behavior of a reverse-flow reactor was studied for the purification of polluted air by catalytic combustion. A heterogeneous one-dimensional model was extended with a heat balance for the reactor wall. An overall heat transport term is included to account for the small heat losses in radial direction. The calculations are compared to experimental data without using fit parameters. The agree...

Light alkanes can be converted to more useful chemicals in noble metal coated monoliths at very short contact times. The short-contacttime reactor is described by detailed models for the flow field, chemistry, and their coupling. The partial oxidation of methane to synthesis gas in a rhodium coated monolith is studied numerically as an example. Keyword: reactor modelling, catalytic partial oxid...

A novel dynamic covalent gel strategy is reported to immobilize an asymmetric catalyst within the channels of a microfluidic flow reactor. A layer of a catalytically active Mn–salen dynamic covalent imine gel matrix was coated onto a functionalized capillary. Mn–salen active moiety was incorporated into dynamic covalent imine gel matrix via the reaction of a chiral Mn–salen dialdehyde unit with...

This work focuses on runaway behaviour of industrial catalytic tube-reactor and presents how decision trees can be used for forecasting the runaway. The steady-state simulator of the reactor and runaway criterion based on Ljapunov’s indirect stability analysis have been used to generate the database used by the decision tree induction algorithm. The extracted logical rules can be used in an ope...

A novel dynamic covalent gel strategy is reported to immobilize an asymmetric catalyst within the channels of a microfluidic flow reactor. A layer of a catalytically active Mn-salen dynamic covalent imine gel matrix was coated onto a functionalized capillary. Mn-salen active moiety was incorporated into dynamic covalent imine gel matrix via the reaction of a chiral Mn-salen dialdehyde unit with...

Hydrogen is the preferred fuel for fuel cells due to high reactivity for electrochemical reaction at anode. In the present study, a three dimensional CFD (Computational Fluid Dynamics) code was developed and validated to simulate the performance of a catalytic monolith fuel processor used for hydrogen generation. Methane autothermal reforming on 5% Ru/ -Al2O3 catalyst was selected as the reacti...

AWract-A reaction-transport model that combines gas-phase reactions mcurting within interstitial and intrapellet voids with surface reactions occurring on catalytic sites was used to descritm the oxidative coupling or methane in packed-bed reactors, a typical example or bimodal (h~ogeneous-heterogeneous) reactjon systcma. A kinetic model for gas-phase reactions was a-bled from available literat...