BACKGROUND The current study evaluates the mortality of 2,354 workers first employed at a Baltimore chromate production plant between 1950 and 1974. METHODS The National Death Index (NDI Plus) was used to determine vital status and cause of death. Cumulative chromium (VI) exposure and nasal and skin irritation were evaluated as risk factors for lung cancer mortality. RESULTS There are 91,18...

In the different compartments of the environmental chromium occurs mainly in the oxidation states (III) and (VI). Although Cr(III) is an essential trace element for humans, Cr(VI) is highly cancerogenic and mutagenic. It is, therefore, necessary for risk assessment not only to determine total chromium, but also to determine chromium species, especially Cr(VI). Hexavalent chromium can be determi...

Biosorption is a process, which represents a biotechnological innovation as well as a cost effective excellent tool for removing heavy metals from aqueous solutions. The kinetics and equilibrium of the biosorption of Chromium (VI) from aqueous solution were investigated using immobilized mixed biosorbents of Annona squamosa seeds and Aspergillus niger in a batch system. The biosorption characte...

Chromium contamination in the area of the Radomka river basin in Poland has lead to significant environmental problems. Therefore, chromium redox transformations were investigated in the aquatic environment under conditions as close to natural as possible at intermediate pH and in the presence of original bottom sediment and dissolved oxygen. Reduction of Cr(VI) in the Radomka river water occur...

Heavy metals are the intrinsic component of the environment with both essential and nonessential types. Their excessive levels pose a threat to plant growth and yield. Also, some heavy metals are toxic to plants even at very low concentrations. The present investigation (a pot experiment) was conducted to determine the affects of varying chromium(VI) levels (0.0, 0.5, 1.0, 2.0, and 4.0 mg chrom...

Peroxochromium(IV) complexes are putative DNA-damaging and mutagenic agents in chromium(VI)-mediated carcinogenesis. The reaction between aquaethylenediaminebis(peroxo)chromium(IV) and glutathione at neutral pH exhibits a cyclic redox process displaying a persistent recycling of Cr(IV) and Cr(VI) with the intervention of chromium(V) intermediates. The coordination by a glutathione molecule trig...

Chromium in fumes generated in work environments including sites of welding work appears in various and complex states. Determination of chromium speciation in samples is useful for estimating the toxicity of such fumes. In the present study, determination of chromium speciation in chromium fumes prepared using a plasma metal sprayer, which are regarded as a model of actual fumes, was carried o...

Chromium is generated from several industrial processes. It occurs in different oxidation states, but Cr(III) and Cr(VI) are the most common ones. Cr(VI) is a toxic, soluble environmental contaminant. Some bacteria are able to reduce hexavalent chromium to the insoluble and less toxic Cr(III), and thus chromate bioremediation is of considerable interest. An indigenous chromium-reducing bacteria...

The isothermal isotopic exchange reaction of O2 with 16O of chromium(VI) oxide supported on zirconia, alumina, and titania has been investigated with in situ laser Raman spectroscopy. The isotopic exchange reaction is dependent on the support type, the Cr loading, and the reaction temperature. Complete isotopic exchange of chromium(VI) oxide with O2 is difficult to achieve and requires several ...