Nanoporous gold (np-Au), because of its high surface area-to-volume ratio, excellent conductivity, chemical inertness, physical stability, biocompatibility, easily tunable pores, and plasmonic properties, has attracted much interested in the field of nanotechnology. It has promising applications in the fields of catalysis, bio/chemical sensing, drug delivery, biomolecules separation and purific...

Soil testing is the basis for nutrient recommendation and formulated fertilization. This study presented a brief overview of potentiometric electrochemical sensors (ISE and ISFET) for soil NPK detection. The opportunities and challenges for electrochemical sensors in soil testing were

in the present study, five modeling approaches of ra, mlp, mnn, gff, and canfis were applied so as to estimate the radial overcut values in electrochemical drilling process. for these models, four input variables, namely electrolyte concentration, voltage, initial machining gap, and tool feed rate, were selected. the developed models were evaluated in terms of their prediction capability with m...

in this work, electrochemical methods such as tafel polarization and electrochemical impedance spectroscopy (eis) were used to study the inhibition efficiency of nettle leaves hydroalcoholic extract as a green corrosion inhibitor of api 5l carbon steel in 0.5 m h2so4 solution. the results showed that the inhibition efficiency was increased with increasing the concentration of the extract and th...

We have developed electrochemical liquid cells for transmission electron microscopy (TEM), which allows imaging of electrochemical processes in liquid electrolytes with high spatial resolution in situ (Fig. 1). Using this set up, we study electrochemical deposition and dissolution of lead dendrites on gold electrodes immersed in an aqueous solution of lead nitrate. Observation reveals lead dend...

This paper describes the synthesis and application of a novel ferrocene (Fc) label that can be efficiently attached to oligonucleotides. We demonstrate how pulse electrochemical methods can be used to measure very low concentrations of ferrocene label and, importantly, show good electroanalytical discrimination between a labelled oligonucleotide and an enzyme digested labelled oligonucleotide, ...

An electroactive nitrospiropyran-substituted polyterthiophene, poly(2-(3,3''-dimethylindoline-6'-nitrobenzospiropyranyl)ethyl 4,4''-didecyloxy-2,2':5',2''-terthiophene-3'-acetate), has been synthesized for the first time. The spiropyran, incorporated into the polymer backbone by covalent attachment to the alkoxyterthiophene monomer units, leads to multiple colored states as a result of both pho...

The strongly nonlinear switching kinetics of electrochemical metallization memory (ECM) cells are investigated using an advanced 1D simulation model. It is based on the electrochemical growth and dissolution of a Ag or Cu filament within a solid thin film and accounts for nucleation effects, charge transfer, and cation drift. The model predictions are consistent with experimental switching resu...