Spatial restrictions around catalytic sites, provided by molecular-sized micropores, are beneficial to reaction selectivity but also inherently limit diffusion. The molecular transport can be enhanced by introducing meso- and macropores. However, the impact of this extraframework porosity on the local nanoscale reactivity is relatively unexplored. Herein we show that the area of enhanced reacti...

The effects of adding of a range of organic amendments (biosolids, spent mushroom compost, green waste compost and green waste-derived biochar), at two rates, on some key chemical, physical and microbial properties of bauxite processing sand were studied in a laboratory incubation study. Addition of all amendments tended to decrease bulk density and macroporosity but increase total porosity, av...

Ocean acidification is predicted to impact ecosystems reliant on calcifying organisms, potentially reducing the socioeconomic benefits these habitats provide. Here we investigate the acclimation potential of stony corals living along a pH gradient caused by a Mediterranean CO2 vent that serves as a natural long-term experimental setting. We show that in response to reduced skeletal mineralizati...

Fluid catalytic cracking (FCC) particles account for 40 to 45% of worldwide gasoline production. The hierarchical complex particle pore structure allows access of long-chain feedstock molecules into active catalyst domains where they are cracked into smaller, more valuable hydrocarbon products (for example, gasoline). In this process, metal deposition and intrusion is a major cause for irrevers...

Abstract Earthworms are “ecosystem engineers” that improve soil water and nutrient content, macroporosity, aeration, provide suitable habitats for microbial populations. This study aimed at defining if the presence of epigeic earthworms ( Eisenia sp.) affected growth development two plant species Brassica oleracea Vicia faba ) via modifications chemico-physical properties. A mesocosm experiment...

Sea-ice ridges constitute a large fraction of the ice volume in Arctic Ocean, yet we know little about evolution these masses. Here examine thermal and morphological an first-year sea-ice ridge, from its formation to advanced melt. Initially mean keel depth was 5.6 m sail height 0.7 m. The initial rubble macroporosity (fraction seawater filled voids) estimated at 29% drilling 43%–46% buoy tempe...

The mass transport of solutes through hydrogels is an important design consideration in materials used for tissue engineering, drug delivery, and protein arrays used to quantify protein concentration and activity. We investigated the use of poly(ethylene glycol) (PEG) as a porogen to enhance diffusion of macromolecules into the interior of polyacrylamide and PEG hydrogel posts photopatterned wi...

We show that the honeycomb out-of-plane model derived by Gibson and Ashby can be applied to describe the compressive behavior of unidirectional porous materials. Ice-templating allowed us to process samples with accurate control over pore volume, size, and morphology. These samples allowed us to evaluate the effect of this microstructural variations on the compressive strength in a porosity ran...