an iodide ion-selective pvc membrane sensor based on copper (π)-bis-nphenilsalicyldenaminatocomplex as a novel sensing material is successfully developed. theelectrode showed a good selectivity for iodide ion with respect to common inorganic anions. thesensor exhibited a good linear response with slope of _58.6 ± 0.4 mv per decade over theconcentration range of 5.0 × 10-6 to 1.0 × 10-1 mol l-1,...

a new poly(vinylchloride) membrane sensor for cr3+ ions based on di (benzylamino)glyoxime asan ionophore was prepared. the electrode has a linear dynamic range 1×10-6-1×10-1 mol l-1,with anernstian slope of 20.3 ± 0.5 mv per decade and a detection limit of 2×10-7. it has a fast responsetime of

the electrocatalysis of the oxygen reduction reaction (orr) on carbon supportedpt-v (1:1) catalyst in polymer electrolyte fuel cells (pefc) was investigated. atan oxygen pressure of one atm an enhanced electrocatalytic property of pt-v/ccompared with pt/c is revealed. these results indicate the occurrence of adifferent electrocatalytic mechanism for the orr on pt/c and pt-v/c. anincrease of mas...

In this work we introduce a practical use of synthesized Schiff base metal complex in sensing application. A new perchlorate-selective electrode based on the complex N, N'-4-nitro-phenylmethanebis-(salicylaldiminato) copper (II) [CuL] as the membrane carrier was developed. The electrode exhibits a good  Nernstian slope of -55.0 ± 1.0 mV/decade and a linear range of  for perchlorate. The lim...

in order to preparing strontium ion selective electrode 6-(4- nitropheny1)-2-pheny14, 4- dipropy1-3, 5-diaza-bicyclo [3, 1, 0] hex-2-ene (npdbh) was used as an ionophore. this electrode responds to sr (ii)ion with a sensitivity of 28.2 ± 0.5 mv/decade over the range 1.0 x 10-6 to 1.0 mat ph 3.0-10.0. thelimit of detection was 2.4 x 10-7 m. the influences of membrane composition, the ph of the t...

a physic-mathematical model has been developed that is suitable for biosensors incorporating membranes and bisubstrate enzymes. the set of equations regarding the transport of reactants across the membrane, the bisubstrate enzymatic reaction, back diffusion of reactants and reaction products, are written down and simultaneously solved and transient response of the electrode is determined as a f...

This paper reports the performance of nickel oxide based electrode in alkaline anion exchange membrane water electrolysis. The membrane used is polystyrene based alkaline membrane and the electrode used is Nickel as cathode and Nickel oxide as anode. The electrochemical activity of the Nickel oxide is high compared to uncoated electrode. The AWE membrane electrode gave high current density at 3...

In order to study the Cu(II) ion selective electrode, an optimized membrane was prepared by mixing of 30 mg of PVC powdered, 5 mg of considered ionophore, 60 mg of plasticizer and 5 mg of additive. The sensor showed a near Nernstian response for Cu(II) ions over a concentration range from 1.0×0-6 –1.0×0-2 M with a slope of 28.90.5 mV per concentration decade with a working pH range of 3.5-6.3. ...