Simple distillation columns with ideal vapor-liquid equilibrium may display multiple steady-state solutions. Two fundamentally different sources for the multiplicity are presented. Both bring about the unexpected result that increasing reflux makes separation worse in the top part of the column. It corresponds to an unstable operating point. The first type of multiplicity is found for columns w...

In this work, we report the thermodynamic and ultrasonic properties of ascorbic acid (vitamin C) in water and in presence of newly synthesized ammonium based protic ionic liquid (diethylethanolammonium propionate) as a function of concentration and temperature. Apparent molar volume and apparent molar isentropic compression, which characterize the solvation state of ascorbic acid (AA) in presen...

In this study, Chemical Oxygen Demand (COD) from a pharmaceutical wastewater (PhW) was reduced by several techniques such as electro-Fenton (EF), photo electro-Fenton (PEF) and activated sludge (AS) processes and the obtained data were compared with each other. The effects of several parameters such as pH, current density, H2O2/Fe2+ molar ratio, volume ratio of ...

We visit the standard procedure for analyzing the optical spectrum of Ho doped tellurite glass has been studied. The glass was formed using a composition 79% Te O2 + 20% Li2 CO2 + 1% Ho O2. I density and refractive index were measured and used to calculate various physical properties such as, rare earth concentration, mean atomic volume, electric polarization, ionic radius, molar refractivity, ...

The ideal relative permittivity of liquid mixtures is demonstrated to be a volume-fraction-weighted average of the pure-component relative permittivities. This generalised-thermodynamics result is used to define the molar electric dipole, permittivity, dielectric polarization and electric susceptibility of thermodynamically ideal liquid mixtures and the corresponding excess properties. A hyperb...

The diffusion coefficients and fluorescence polarization properties of actin subjected to a known shear have been determined both during and after polymerization, using a modification of a cone-plate Wells-Brookfield rheometer that allows monitoring of samples with an epifluorescence microscope. Fluorescence polarization and fluorescence photobleaching recovery experiments using rhodamine-label...

polarization for au/pb(zr ti )o /yba cu o ferroelectric capacitor has been studied and measured by pulse method. a sequence of pulses with amplitudes varying from 0 to 10 volts in 2 volt steps is applied and a conventional polarization curve is obtained by integrating the charge flow from the polarization switching induced by the voltage ramp. a value of 25?c/cm2 is measured for the saturated p...

introduction: the human skin is an active medium from the optical point of view. therefore, the diagnostic and therapeutic techniques employing light are increasing. current optical techniques are based on the measurement of the intensity of reflected absorbed or backscattered light from or within skin. studies have shown that biological tissues, and in particular skin, demonstrate polarization...

This study examines the properties of a 4 × 2 matrix of aqueous cations and anions at concentrations up to 8.0 M. The apparent molar water volume, as calculated by subtracting the mass and volume of the ions from the corresponding solution density, was found to exceed the molar volume of ice in many concentrated electrolyte solutions, underscoring the nonideal behavior of these systems. The sol...