Triple-stranded dinuclear nickel(ii) complexes of the meso-helicate type have been obtained from the new N,N'-1,3-phenylenebis(pyrazine-2-carboxamidate) ligand; they possess a multielectron redox behaviour featuring up to four stepwise, one-electron oxidation reactions of the two ferromagnetically coupled Ni(II) ions to afford the putative high-valent dinickel(iii) and dinickel(iv) species, as ...

A new dimensional scaling method for the calculation of excited states of multielectron atoms is introduced. By including the principle and orbital quantum numbers in the dimension parameter, we obtain an energy expression for excited states including high angular momentum states. The method is tested on He, Li, and Be. We obtain good agreement with more orthodox quantum mechanical treatments e...

The physics of multielectron atoms in strong external fields is substantially more complex than that of hydrogen. In particular, puzzling new resonances were recently observed in experimental photoabsorption spectra of diamagnetic helium and in quantum mechanical calculations of diamagnetic Rydberg atoms. We compute spectra in the framework of periodic-orbit theory and show that the new resonan...

Single-electron charging effects similar to those in small-area metallic tunnel junctions should take place in semiconductor heterostructures, in particular, small-area quantum wells. Our analysis shows that dc current-voltage characteristics of such a well should exhibit an interplay between single-electron charging and energy-quantization effects. Relative magnitude of the single-electron cha...

The energy change per electron in a chemical or physical transformation, ΔE/n, may be expressed as Δχ̅ + Δ(VNN + ω)/n, where Δχ̅ is the average electron binding energy, a generalized electronegativity, ΔVNN is the change in nuclear repulsions, and Δω is the change in multielectron interactions in the process considered. The last term can be obtained by the difference from experimental or theoreti...

We have investig4ated multielectron bubbles (with charges Z,,, 10 6 electrons) in normal liquid He. The drift velocity in an electric field and the charge of the bubbles were measured simultaneously. We found the drag coeJficient to be over an order of magnitude higher than expected from ordinary hydrodynamics. The velocities did not show a correlation with the charge and could vary up to a fac...

The theory of ground state and excited state energies calculations of multielectron quantum dot with hydrogenic impurity within the effective mass approximation has been given. Results show that ground and excited state energies decrease with dot radius. In the present paper, calculation has been carried out for two electron quantum dot. The effect of magnetic field on first excited state for d...

In this paper, we study the effect of single Boron/Nitrogen impurityatom on electronic properties of a silicene nano flake. Our calculations are basedon density functional theory by using Gaussian package. Here, one Si atom insilicene nano flake substitutes with a Boron/Nitrogen atom. The results show thatsubstitution of one Si atom with single Boron/Nitrogen atom increases distanceof impurity ...