A challenge for scaling up hydrogen production by raw bio-oil steam reforming (SR) is the rapid catalyst deactivation that strongly sensitive to temperature and composition. This work studies combined effect of both variables on stability a Ni/Al2O3 with high Ni dispersion in internal external surfaces particles, obtained reduction NiAl2O4. The composition modified (i) removal phenolic compound...

The steam reforming of bio-oil is a promising and economically feasible technology for the sustainable H2 production, yet with main challenge designing highly active stable catalysts. This work aimed to study deactivation mechanism NiAl2O4 spinel derived catalyst, role Ni alumina sites in this appropriate reaction conditions attenuate deactivation. tests were carried out fluidized bed reactor p...

H2 production through dry reforming of methane (DRM) is a hot topic amidst growing environmental and atom-economy concerns. Loading Ni-based reducible mixed oxide systems onto thermally stable support reliable approach for obtaining catalysts good dispersion high stability. Herein, NiO was dispersed over MOx-modified-γ-Al2O3 (M = Ti, Mo, Si, or W; x 2 3) incipient wetness impregnation followed ...

The choice of appropriate reactors and reforming strategies is key to make progresses on scaling up H2 production processes from raw bio-oil. This work compares the performance (conversion, product yields deactivation) packed-bed fluidized-bed (PBR FBR, respectively) using a NiAl2O4 spinel derived catalyst for bio-oil via steam (SR) sorption enhanced SR (SESR, with dolomite capture CO2). experi...

Abstract: as magnetic materials, semiconductors, pigments, catalysts, refractories and electronic ceramics. In this paper, wereported the preparation of NiAlThe resulting powder was chracterized by XRD, particle size analysis and SEM. The XRD patterns show that thecombustion technique was excellent to prepare single – phased cubic NiAlfound to be around 14 nm. From the particle size analysis, i...