The effect of hydrotropes on the geometry of reverse water-in-oil AOT-microemulsions is investigated as a function of water content, and hydrotrope additive architecture. SANS reveals that hydrotropes induce cylindrical morphologies which transition to ellipsoidal and then spherical geometries with increasing water content (w). The length of the elongated particles appeared to show some depende...

The oil production rate decreases rapidly after a short period of high yield from acidizing or fracturing in low-permeability reservoirs. In this paper, nanospheres are applied before the step, which possess ability to absorb water and expand layer, reducing flow capacity bottom finally enhancing recovery. plugging performance is investigated by nanosphere displacement experiments cores sand-pa...

A liquid-glass transition was observed experimentally in a new system, an oil-in-water emulsion. Dynamic light scattering was employed to obtain the intermediate scattering function f(q,t) for a range of volume fractions f and scattering vectors q. The results are compared with predictions of the mode coupling theory. While the usual idealized version of the theory provides accurate fits to the...

We report the creation of air/oil/water interfaces with variable-thickness oil films using polyisobutylene-based (PIB) surfactants cospread with long-chain paraffinic alkanes on clean water surfaces. The resultant stable oil layers are readily measurable with simple surface techniques, exhibit physical densities the same as expected for bulk oils, and are up to approximately 100 A thick above t...

The existence of the bottom oil–water transition zone (BTZ) greatly impairs performance conventional steam-assisted gravity drainage (SAGD) process and its mitigation measures are very limited. In order to accelerate oil production decrease Steam-to-Oil Ratio (SOR), a promising technology involving steam drive (SDGD) by placing dual-horizontal wells with high permeability in BTZ was systematica...

– Ideal bosons and classical ring polymers formed via self-assembly, are known to have the same partition function, and so analogous phase transitions. In ring polymers, the analogue of Bose-Einstein condensation occurs when a ring polymer of macroscopic size appears. We show that a transition of the same general form occurs within a whole class of systems with self-assembly, and illustrate it ...

Papers published in Hydrology and Earth System Sciences Discussions are under open-access review for the journal Hydrology and Earth System Sciences Abstract Interactions between groundwater and surface water play a critical role in the functioning of riparian ecosystems. In the context of sustainable river basin management it is crucial to understand and quantify exchange processes between gro...

A new method of supramolecular polymerization at the water-oil interface is developed. As a demonstration, an oil-soluble supramonomer containing two thiol end groups linked by two ureidopyrimidinone units and a water-soluble monomer bearing two maleimide end groups are employed. Supramolecular interfacial polymerization can be implemented by a thiol-maleimide click reaction at the water-chloro...

A theoretical model for carbon dioxide (CO2) migration in tilted aquifers with groundwater flow is presented to evaluate the injection of CO2 into a geological formation. Capillary force in the flow of two immiscible fluids in a porous medium creates a saturation transition zone, where the saturation changes gradually. A vertical equilibrium assumption is employed to solve for the capillary pre...