Sulfonic acid functionalized nanoporous silica (SBA-Pr-SO3H) with a pore size of 6 nm catalyzed three component coupling of aromatic aldehydes, urea and ethyl acetoacetate to afford the corresponding dihydropyrimidinones under solvent free condition. This new protocol for Biginelli reaction has important advantages such as green synthesis, short reaction time, easy isolation and high yields of ...

Phthalimide was reacted with chlorosulfonic acid to give sulfonic acid-functionalized phthalimide (SFP), which characterized by 1H NMR, 13C NMR, FT-IR, XRD (X-ray diffraction), SEM (scanning electron microscopy), EDX (energy-dispersive X-ray), mass, TG (thermogravimetry) and DTG (derivative thermal gravimetry) spectra. Afterward, its catalytic activity was examined for the condensation of aryla...

a simple and efficient method for synthesis of tetrahydropyrimido[4,5-b]quinoline derivatives via three component reaction of aromatic aldehydes, dimedone and 6-amino uracil derivatives using a catalytic amount of sulfonic acid functionalized nanoporous silica (sba-15-pr-so3h) is described. the advantages of this method are easy and clean work-up, high yield, mild reaction condition, reusable c...

Selective Proton Transport In article number 2215109, Tongwen Xu, Liang Ge, Xingya Li, and co-workers report a series of dibenzo-18-crown-6 functionalized sulfonated poly(biphenyl alkylene) membranes. The membranes possess synergistic hydrophilic networks induced by bi-functional sites (crown ether sulfonic-acid group), increasing selective proton transport, providing efficient acid recovery in...

Local differences in surface hydrophilicities/hydrophobicities of propyland arene-sulfonic-acid modified mesoporous silica and organosilica catalysts have been compared and correlated with their bulk catalytic properties for aqueous-sensitive organic reactions. Syntheses of propyland arene-SO3H-modified mesoporous silicas and organosilicas yield materials with different hydrophilicities, especi...

The effects of surface modifications of multi-walled carbon nanotubes (MWCNTs) on their dispersibility in different solvents and poly (ether ether ketone) (PEEK) have been studied. MWCNTs were treated by mixed acids to obtain acid-functionalized MWCNTs. The acid-functionalized MWCNTs were modified with six different chemical agents separately, 1,6-diaminohexane, hexadecyl trimethyl ammonium bro...

A new building block containing an imidazolium salt was synthesized and used for the construction of supramolecular networks with metal ions. We discovered the concomitant formation of the N-heterocyclic carbene-copper complex (CN = 2) in the self-assembly of imidazolium dicarboxylates and copper nitrates in N,N-dimethylformamide under heating. The proton in the 2 position of the imidazolium sa...

The acid dyes are one of the most widely used commercial dyes used in the textile industries. This work investigates the ability of magnetite nanoparticles functionalized with imidazolium based ionic liquid as an efficient sorbent for removal of the Acid Blue 113 from wastewater. Fourier Transform Infrared Spectroscopy FT-IR, X-ray diffraction XRD and Transmission Electron Microscopy TEM were u...