The field of gas phase photochemistry has progressed explosively in the past few decades due to the development of ultra fast high power lasers. Unique properties of lasers such as monochromaticity, coherence, tunability over a wide wavelength range and high intensity makes them a powerful pump and probe tool for a number of spectroscopic as well as photochemical studies like laser induced fluo...

using ultrasonic devices in endodontics can enhance the antibacterial and tissue dissolving ability of different root canal irrigants such as sodium hypochlorite (naocl) which is the most common irrigant with excellent antibacterial and tissue dissolving abilities. however, due to its high surface tension, its penetration into the irregularities of the root canal system is a challenge. the purp...

A series of photochemical reactions are assessed under the environmental aspect by using Eissen and Metzger’s EATOS (environmental assessment tool for organic syntheses) method and are compared with strictly analogous thermal processes. These include C–C bond-forming reactions (arylation and alkylation) and selective oxidation and reduction reactions. In most cases, the photochemical method is ...

Both the spectrum and correlation characteristics are important in constructing excitation sequences to realize the multichannel ultrasonic sensors working together. For LFM excitation sequence, there should not be too many simultaneously fired ultrasonic sensors, because of the limited available frequency band of the ultrasonic ranging system. The optimized CFM excitation sequences are propose...

In ultrasonic tube hydroforming, the tube is hydro formed while the ultrasonic vibration is applied to the die. Prior studies provide experimental proof that ultrasonic tube hydroforming reduces corner radius, improves lubrication and uniform thickness. Use of ultrasonic vibration can decrease friction at the tube-die interface. Few attempts have been made to analyze the wire drawing while the ...

In this paper, we discuss the results of our recent studies on the molecular mechanism, which stand at the basis of the photochemical processes occurring in photobiological systems. These results are obtained using modern, robust, and fairly accurate high-level quantum chemical methods.

The reactivity of higher plant derived 3-oxy-triterpenoids to sunlight was investigated using a series of pure reference standards both under simulated and real solar exposure. The majority of the exposed compounds showed reactivity to light, particularly to simulated sunlight and among others generated seco-derivatives. While photochemical processes have been suggested for the formation of suc...

In this work, the molecular structure, infrared spectrum and UV photochemistry of 2-methyl-2H-tetrazol-5-amine (2MTA) isolated in solid argon (10 K) were investigated. The experimental studies were supported by extensive DFT(B3LYP)/6-311++G(d,p) calculations. The infrared spectrum of matrix-isolated 2MTA was fully assigned and correlated with structural properties. Taking into consideration the...