Nitrogen-containing compounds are important chemical entities, many of which show unique bioactivity. In view of this their efficient synthesis is an important issue in the development of pharmaceutically active molecule. However, the handling of highly-polar nitrogen-containing compounds is often problematic, and furthermore the propensity of basic nitrogen compounds to undergo oxidation limit...

Thiobacillus denitrificans is physiologically similar to the type species of the genus Thiobacillus, Thiobacillus Thioparus, and both are located in the beta-subclass of the Proteobacteria. T. denitrificans is distinguished from all other Thiobacillus species by its ability to grow as a facultatively anaerobic chemolithotroph, coupling the oxidation of inorganic sulfur compounds to the reductio...

In all of its known connections nitrogen retains a valence shell electron count of eight therefore satisfying the golden rule of chemistry - the octet rule. Despite the diversity of nitrogen chemistry (with oxidation states ranging from + 5 to -3), and despite numerous efforts, compounds containing nitrogen with a higher electron count (hypervalent nitrogen) remain elusive and are yet to be syn...

Conn (1942) observed that Alcaligenes faecalis required organic nitrogen, but as observed by Porter (1946) no report was found of a study of nitrogen compounds suitable for continued growth of A. faecalis. It was reported, however, that this organism grew in a medium containing NH4 lactate as a source of nitrogen and carbon (Braun and Cahn-Bronner, 1921), and used NH4NO3, asparagine, cysteine, ...

In this study, the classes and structures of nitrogen species in coker gas oil (CGO) are characterized by electrospray ionization (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) combined with Fourier transform infrared (FT-IR) spectroscopy. The results demonstrate that the m/z of basic and non-basic nitrogen compounds ranges from 180 to 560 and from 200 to 460, res...

Recently, alternative detection methods such as chemiluminescent nitrogen detection (CLND) have been coupled successfully with HPLC for quantification. This detector produces a signal proportional to the number of moles nitrogen present in the compound. Sample concentration of compounds with a known formula can be determined by use of an external calibration standard such as caffeine. Hence, th...