In this work, an equation of state has been utilized for thermodynamic modeling of aqueous electrolyte solutions. The proposed equation of state is a combination of simplified statistical associating fluid theory (SAFT) equation of state (similar to simplified PC-SAFT) to describe the effect of short-range interactions and mean spherical approximation (MSA) term to describe the effect of long-r...

R-1243zf is a new refrigerant that could replace R-134a. Its thermodynamic properties represented in the equation of state (EOS) play an essential role analyzing and designing thermal systems. The EOS exists without including caloric property data due to unavailable during development time. New was developed explicitly Helmholtz free energy optimized represent experimental accurately maintain c...

Thermophysical properties of fluorine are interesting because of its applications in different areas of technologyand industry. The computations of thermodynamic properties were performed with the GMA equation of stateunder critical conditions. The present work reports calculations of density, volumetric, and thermodynamicproperties of liquid fluorine on extended ranges of pressure and temperat...

Thermodynamic consistency test of isothermal vapor-liquid equilibrium (VLE) data of various binary systems containing Carbon dioxide (CO2)/Room temperature ionic liquids (RTILs) have been investigated in wide ranges of pressures in each isotherm precisely. In this paper Generic van der Waals (GvdW) equation of state (EoS) coupled with modified van der Waals Berthelot mixing rule has ...

a method for predicting liquid densities of binary mixtures from heat of vaporization and liquid densityat boiling point temperature (δhvap and n b ρ ) as scaling constants, is presented. b2(t) follows a promisingcorresponding-states principle. calculation of α(t) and b(t), the two other temperature-dependentconstants of the equation of state, are made possible by scaling. as a result δhvap and...

The local thermodynamics of a system with long-range interactions in d dimensions is studied using the mean-field approximation. Long-range interactions are introduced through pair interaction potentials that decay as a power law in the interparticle distance. We compute the local entropy, Helmholtz free energy, and grand potential per particle in the microcanonical, canonical, and grand canoni...

an analytical equation of state has been previously modified by papari et al. for representing the volumetric properties of molecular fluids. however the performance of that eos has not been yet well investigated for refrigerant fluids. this study extended that equation to 19 liquid refrigerants to predict their densities at isothermal and saturated states. two temperature-independent parameter...

This paper demonstrates the capabilities of the PFGC-MES equation of state (EOS) for calculating the thermodynamic properties in the superheated region for pure refrigerants. In addition the ability of this EOS is also tested for predicting the VLE behavior of binary mixtures. For pure compounds several properties in the superheated region are predicted. The calculated results and the experimen...

A mixing rule for the mixtures of hard-spheres is presented which can be reduced to the standard van der Waals mixing rule at low densities. The effectiveness of the mixing rule for the size and energy parameters of lennard-Jones fluid are examined by combining them with an equation of state to calculate thermodynamic properties. The results of calculation are compared with the molecular dy...