The mineral harmotome (Ba,Na,K)1-2(Si,Al)8O16⋅6H2O is a crystalline sodium calcium silicate which has the potential to be used in plaster boards and other industrial applications. It is a natural zeolite with catalytic potential. Raman bands at 1020 and 1102 cm(-1) are assigned to the SiO stretching vibrations of three dimensional siloxane units. Raman bands at 428, 470 and 491 cm(-1) are assig...

In photosynthesis absorbed sun light produces collective excitations (excitons) that form a coherent superposition of electronic and vibrational states of the individual pigments. Two-dimensional (2D) electronic spectroscopy allows a visualization of how these coherences are involved in the primary processes of energy and charge transfer. Based on quantitative modeling we identify the exciton-v...

The multiple-mode two-dimensional infrared (2D-IR) spectrum in a broad frequency range from 1000 to 3200 cm(-1) of a 1-cyanovinyl acetate solution in CCl(4) is reported. By analyzing its relative orientations of the transition dipole moments of normal modes that cover vibrations of all chemical bonds, the three-dimensional molecular conformations and their population distributions of 1-cyanovin...

We present a simple tight-binding model for the two-dimensional energy bands of polyacene field-effect transistors and for the coupling of these bands to lattice vibrations of their host molecular crystal. We argue that the strongest electron-phonon interactions in these systems originate from the dependence of intermolecule hopping amplitudes on collective molecular motion, and introduce a gen...

The present paper is aimed to study an exact analysis of the free vibrations of a simply supported, homogeneous, transversely isotropic, cylindrical panel based on three-dimensional generalized theories of thermoelastic diffusion. After applying the displacement potential functions in the basic governing equations of generalized thermoelastic diffusion, it is noticed that a purely transverse mo...

In this research, dynamic analysis of the rotational slender axially moving string is investigated. String assumed as Euler Bernoulli beam. The axial motion of the string, gyroscopic force and mass eccentricity were considered in the study. Equations of motion are derived using Hamilton’s principle, resulting in two partial differential equations for the transverse motions. The equations are ch...

Three-dimensional reciprocal-space maps of a single SiGe island around the Si(004) Bragg peak are recorded using an energy-tuning technique with a microfocused X-ray beam with compound refractive lenses as focusing optics. The map is in agreement with simulated data as well as with a map recorded by an ordinary rocking-curve scan. The energy-tuning approach circumvents both the comparatively la...

A simulation study shows that early protein folding events may be investigated by using a recently developed family of nonlinear infrared techniques that combine the high temporal and spatial resolution of multidimensional spectroscopy with the chirality-specific sensitivity of amide vibrations to structure. We demonstrate how the structural sensitivity of cross-peaks in two-dimensional correla...

Wiper is a device to wipe out dirt and raindrops from the windscreen. Hence, when a wiper system is operated, it has a potential to generate unwanted noise and vibration level. Reversal is one of the noise and vibration generated during the wiper operations. It is a medium frequency and self excited vibration that is often generated before and vice versa the direction. This leads to poor visibi...

This paper presents the use of three-dimensional finite elements coupled with infinite elements to investigate the ground vibrations at the surface in terms of the peak particle velocity (PPV) due to construction of the first bore of the Dublin Port Tunnel. This situation is analysed using a commercially available general-purpose finite element package ABAQUS. A series of parametric studies is ...